Novel azo octupoles with large first hyperpolarizabilities

Myung Ja Lee, Mingjun Piao, Mi Yun Jeong, Sang Hae Lee, Kyung Min Kang, Seung-Joon Jeon, Tong Gun Lim, Bong-Rae Cho

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37 Citations (Scopus)

Abstract

Novel two-dimensional octupoles containing azo groups and their oligomers have been synthesized and their first hyperpolarizabilities were determined. The λ max and β(0) values of azo octupoles are nearly the same regardless of the nature of the bridge or the conjugation length. On the other hand, 1,3,5-tricyano-2,4,6-tris-[4-(p-diethylaminostyryl)styryl]benzene has a larger β(0) value than the corresponding azo analogue probably due to the more efficient conjugation ability of C=C compared with the N=N bond. The β(0)/MW of the octupoles are larger than the corresponding dipoles, whereas those of the azo octupoles are comparable to the latter. Also, retention of monomeric β(0) is observed in the octupolar oligomers.

Original languageEnglish
Pages (from-to)1030-1037
Number of pages8
JournalJournal of Materials Chemistry
Volume13
Issue number5
DOIs
Publication statusPublished - 2003 May 1

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Science(all)
  • Materials Chemistry

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  • Cite this

    Lee, M. J., Piao, M., Jeong, M. Y., Lee, S. H., Kang, K. M., Jeon, S-J., Lim, T. G., & Cho, B-R. (2003). Novel azo octupoles with large first hyperpolarizabilities. Journal of Materials Chemistry, 13(5), 1030-1037. https://doi.org/10.1039/b300777d