Observation of bicarbonate in calcite by NMR spectroscopy

Jian Feng, Young Jae Lee, Richard J. Reeder, Brian L. Phillips

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

We show that the signal observed in 13C{1H} cross-polarization magic-angle-spinning (CP/MAS) NMR spectra of synthetic calcite precipitated at room temperature arises from bicarbonate ion. Although this peak occurs at the same chemical shift as for the bulk carbonate signal, its observation by CP/MAS indicates that it corresponds to carbonate associated with H. The variation in the CP/MAS intensity with contact time shows oscillations characteristic of C-H pairs separated by 1.9(1) Å and remote from other H, consistent with bicarbonate. 13C{1H} heteronuclear correlation spectra indicate that the hydrogen in the bicarbonate groups gives a relatively narrow 1H NMR signal at +7.4 ppm. A peak at this chemical shift is also observed in direct-observe 1H MAS NMR spectra of the synthetic sample, and also in natural biogenic and abiogenic calcite. This 1H chemical shift indicates a moderate hydrogen bonding interaction d(OH...O) ≈ 1.85 Å, which suggests significant structural relaxation occurs near the bicarbonate.

Original languageEnglish
Pages (from-to)957-960
Number of pages4
JournalAmerican Mineralogist
Volume91
Issue number5-6
DOIs
Publication statusPublished - 2006 May 1
Externally publishedYes

Fingerprint

Calcium Carbonate
Bicarbonates
calcite
bicarbonate
Nuclear magnetic resonance spectroscopy
Magic angle spinning
nuclear magnetic resonance
carbonates
Chemical shift
spectroscopy
polarization
Carbonates
cross polarization
Nuclear magnetic resonance
Polarization
metal spinning
chemical equilibrium
hydrogen
carbonate
Structural relaxation

Keywords

  • Bicarbonate
  • Calcite
  • Hydrogen bond
  • Nacohlite
  • NMR spectroscopy
  • Trona

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics

Cite this

Observation of bicarbonate in calcite by NMR spectroscopy. / Feng, Jian; Lee, Young Jae; Reeder, Richard J.; Phillips, Brian L.

In: American Mineralogist, Vol. 91, No. 5-6, 01.05.2006, p. 957-960.

Research output: Contribution to journalArticle

Feng, Jian ; Lee, Young Jae ; Reeder, Richard J. ; Phillips, Brian L. / Observation of bicarbonate in calcite by NMR spectroscopy. In: American Mineralogist. 2006 ; Vol. 91, No. 5-6. pp. 957-960.
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