Octacyanometalate-based ferrimagnetic MVMnIII (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations

Houng Sik Yoo, Hyun Hee Ko, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Woo Ram Lee, Hyoung Chan Kim, Eui Kwan Koh, Chang Seop Hong

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

Cyanide-bridged MVMnIII (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)8]3- precursors and MnIII Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.

Original languageEnglish
Pages (from-to)5617-5619
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number13
DOIs
Publication statusPublished - 2009 Jul 6

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Magnetic relaxation
Schiff Bases
magnetic relaxation
Cyanides
cyanides
assembling
imines

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Octacyanometalate-based ferrimagnetic MVMnIII (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations. / Yoo, Houng Sik; Ko, Hyun Hee; Ryu, Dae Won; Lee, Jin Wuk; Yoon, Jung Hee; Lee, Woo Ram; Kim, Hyoung Chan; Koh, Eui Kwan; Hong, Chang Seop.

In: Inorganic Chemistry, Vol. 48, No. 13, 06.07.2009, p. 5617-5619.

Research output: Contribution to journalArticle

Yoo, Houng Sik ; Ko, Hyun Hee ; Ryu, Dae Won ; Lee, Jin Wuk ; Yoon, Jung Hee ; Lee, Woo Ram ; Kim, Hyoung Chan ; Koh, Eui Kwan ; Hong, Chang Seop. / Octacyanometalate-based ferrimagnetic MVMnIII (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations. In: Inorganic Chemistry. 2009 ; Vol. 48, No. 13. pp. 5617-5619.
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