Cyanide-bridged MVMnIII (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)8]3- precursors and MnIII Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry