Octacyanometalate-based ferrimagnetic MVMnIII (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations

Houng Sik Yoo, Hyun Hee Ko, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Woo Ram Lee, Hyoung Chan Kim, Eui Kwan Koh, Chang Seop Hong

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48 Citations (Scopus)

Abstract

Cyanide-bridged MVMnIII (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)8]3- precursors and MnIII Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.

Original languageEnglish
Pages (from-to)5617-5619
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number13
DOIs
Publication statusPublished - 2009 Jul 6

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Yoo, H. S., Ko, H. H., Ryu, D. W., Lee, J. W., Yoon, J. H., Lee, W. R., Kim, H. C., Koh, E. K., & Hong, C. S. (2009). Octacyanometalate-based ferrimagnetic MVMnIII (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations. Inorganic Chemistry, 48(13), 5617-5619. https://doi.org/10.1021/ic900879d