Octupolar crystals for nonlinear optics: 1,3,5-Trinitro-2,4,6-tris(styryl)benzene derivatives

Rae Cho Bong Rae Cho, M. Cho, Jae Lee Seung Jae Lee, Hae Lee Sang Hae Lee, Hwa Son Kyung Hwa Son, Hoon Kim Young Hoon Kim, J. Y. Doo, Joon Lee Geon Joon Lee, Im Kang Tae Im Kang, Kyong Lee Yun Kyong Lee, S. J. Jeon

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90 Citations (Scopus)

Abstract

1,3,5-Trinitro-2,4,6-tris(styryl)benzene derivatives 1-3 were synthesized and their optical properties, first hyperpolarizabilities (β), powder SHG efficiencies, and Td, were determined. They exhibited significant β [β(0) = (24-89) × 10-30 esu] and powder SHG values [M/MmNA = 0.2-5.8] as well as high thermal stabilities (Tdi= 210-310 °C).

Original languageEnglish
Pages (from-to)1438-1440
Number of pages3
JournalChemistry of Materials
Volume13
Issue number5
DOIs
Publication statusPublished - 2001

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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    Bong Rae Cho, R. C., Cho, M., Seung Jae Lee, J. L., Sang Hae Lee, H. L., Kyung Hwa Son, H. S., Young Hoon Kim, H. K., Doo, J. Y., Geon Joon Lee, J. L., Tae Im Kang, I. K., Yun Kyong Lee, K. L., & Jeon, S. J. (2001). Octupolar crystals for nonlinear optics: 1,3,5-Trinitro-2,4,6-tris(styryl)benzene derivatives. Chemistry of Materials, 13(5), 1438-1440. https://doi.org/10.1021/cm000816z