Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes

Ana C. Glavan, Ramses V. Martinez, Anand Bala Subramaniam, Hyo Jae Yoon, Rui M D Nunes, Heiko Lange, Martin M. Thuo, George M. Whitesides

Research output: Contribution to journalArticle

100 Citations (Scopus)

Abstract

The fabrication and properties of "fluoroalkylated paper" ("RF paper") by vapor-phase silanization of paper with fluoroalkyl trichlorosilanes is reported. RF paper is both hydrophobic and oleophobic: it repels water (θapp H2O>140°), organic liquids with surface tensions as low as 28 mN m-1, aqueous solutions containing ionic and non-ionic surfactants, and complex liquids such as blood (which contains salts, surfactants, and biological material such as cells, proteins, and lipids). The propensity of the paper to resist wetting by liquids with a wide range of surface tensions correlates with the length and degree of fluorination of the organosilane (with a few exceptions in the case of methyl trichlorosilane- treated paper), and with the roughness of the paper. RF paper maintains the high permeability to gases and mechanical flexibility of the untreated paper, and can be folded into functional shapes (e.g., microtiter plates and liquid-filled gas sensors). When impregnated with a perfluorinated oil, RF paper forms a "slippery" surface (paper slippery liquid-infused porous surface, or "paper SLIPS") capable of repelling liquids with surface tensions as low as 15 mN m-1. The foldability of the paper SLIPS allows the fabrication of channels and flow switches to guide the transport of liquid droplets.

Original languageEnglish
Pages (from-to)60-70
Number of pages11
JournalAdvanced Functional Materials
Volume24
Issue number1
DOIs
Publication statusPublished - 2014 Jan 8
Externally publishedYes

Fingerprint

Liquids
liquids
interfacial tension
Surface tension
forms (paper)
surfactants
fabrication
fluorination
organic liquids
Fabrication
Fluorination
gases
Nonionic surfactants
wetting
blood
lipids
Chemical sensors
Application programs
Surface-Active Agents
permeability

Keywords

  • hydrophobic papers
  • omniphobic papers
  • origami
  • paper SLIPS
  • SLIPS

ASJC Scopus subject areas

  • Biomaterials
  • Electrochemistry
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

Cite this

Glavan, A. C., Martinez, R. V., Subramaniam, A. B., Yoon, H. J., Nunes, R. M. D., Lange, H., ... Whitesides, G. M. (2014). Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes. Advanced Functional Materials, 24(1), 60-70. https://doi.org/10.1002/adfm.201300780

Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes. / Glavan, Ana C.; Martinez, Ramses V.; Subramaniam, Anand Bala; Yoon, Hyo Jae; Nunes, Rui M D; Lange, Heiko; Thuo, Martin M.; Whitesides, George M.

In: Advanced Functional Materials, Vol. 24, No. 1, 08.01.2014, p. 60-70.

Research output: Contribution to journalArticle

Glavan, AC, Martinez, RV, Subramaniam, AB, Yoon, HJ, Nunes, RMD, Lange, H, Thuo, MM & Whitesides, GM 2014, 'Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes', Advanced Functional Materials, vol. 24, no. 1, pp. 60-70. https://doi.org/10.1002/adfm.201300780
Glavan, Ana C. ; Martinez, Ramses V. ; Subramaniam, Anand Bala ; Yoon, Hyo Jae ; Nunes, Rui M D ; Lange, Heiko ; Thuo, Martin M. ; Whitesides, George M. / Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes. In: Advanced Functional Materials. 2014 ; Vol. 24, No. 1. pp. 60-70.
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