Abstract
The fabrication and properties of "fluoroalkylated paper" ("RF paper") by vapor-phase silanization of paper with fluoroalkyl trichlorosilanes is reported. RF paper is both hydrophobic and oleophobic: it repels water (θapp H2O>140°), organic liquids with surface tensions as low as 28 mN m-1, aqueous solutions containing ionic and non-ionic surfactants, and complex liquids such as blood (which contains salts, surfactants, and biological material such as cells, proteins, and lipids). The propensity of the paper to resist wetting by liquids with a wide range of surface tensions correlates with the length and degree of fluorination of the organosilane (with a few exceptions in the case of methyl trichlorosilane- treated paper), and with the roughness of the paper. RF paper maintains the high permeability to gases and mechanical flexibility of the untreated paper, and can be folded into functional shapes (e.g., microtiter plates and liquid-filled gas sensors). When impregnated with a perfluorinated oil, RF paper forms a "slippery" surface (paper slippery liquid-infused porous surface, or "paper SLIPS") capable of repelling liquids with surface tensions as low as 15 mN m-1. The foldability of the paper SLIPS allows the fabrication of channels and flow switches to guide the transport of liquid droplets.
| Original language | English |
|---|---|
| Pages (from-to) | 60-70 |
| Number of pages | 11 |
| Journal | Advanced Functional Materials |
| Volume | 24 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2014 Jan 8 |
| Externally published | Yes |
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Keywords
- hydrophobic papers
- omniphobic papers
- origami
- paper SLIPS
- SLIPS
ASJC Scopus subject areas
- Biomaterials
- Electrochemistry
- Condensed Matter Physics
- Electronic, Optical and Magnetic Materials
Cite this
Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes. / Glavan, Ana C.; Martinez, Ramses V.; Subramaniam, Anand Bala; Yoon, Hyo Jae; Nunes, Rui M D; Lange, Heiko; Thuo, Martin M.; Whitesides, George M.
In: Advanced Functional Materials, Vol. 24, No. 1, 08.01.2014, p. 60-70.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Omniphobic "rF paper" produced by silanization of paper with fluoroalkyltrichlorosilanes
AU - Glavan, Ana C.
AU - Martinez, Ramses V.
AU - Subramaniam, Anand Bala
AU - Yoon, Hyo Jae
AU - Nunes, Rui M D
AU - Lange, Heiko
AU - Thuo, Martin M.
AU - Whitesides, George M.
PY - 2014/1/8
Y1 - 2014/1/8
N2 - The fabrication and properties of "fluoroalkylated paper" ("RF paper") by vapor-phase silanization of paper with fluoroalkyl trichlorosilanes is reported. RF paper is both hydrophobic and oleophobic: it repels water (θapp H2O>140°), organic liquids with surface tensions as low as 28 mN m-1, aqueous solutions containing ionic and non-ionic surfactants, and complex liquids such as blood (which contains salts, surfactants, and biological material such as cells, proteins, and lipids). The propensity of the paper to resist wetting by liquids with a wide range of surface tensions correlates with the length and degree of fluorination of the organosilane (with a few exceptions in the case of methyl trichlorosilane- treated paper), and with the roughness of the paper. RF paper maintains the high permeability to gases and mechanical flexibility of the untreated paper, and can be folded into functional shapes (e.g., microtiter plates and liquid-filled gas sensors). When impregnated with a perfluorinated oil, RF paper forms a "slippery" surface (paper slippery liquid-infused porous surface, or "paper SLIPS") capable of repelling liquids with surface tensions as low as 15 mN m-1. The foldability of the paper SLIPS allows the fabrication of channels and flow switches to guide the transport of liquid droplets.
AB - The fabrication and properties of "fluoroalkylated paper" ("RF paper") by vapor-phase silanization of paper with fluoroalkyl trichlorosilanes is reported. RF paper is both hydrophobic and oleophobic: it repels water (θapp H2O>140°), organic liquids with surface tensions as low as 28 mN m-1, aqueous solutions containing ionic and non-ionic surfactants, and complex liquids such as blood (which contains salts, surfactants, and biological material such as cells, proteins, and lipids). The propensity of the paper to resist wetting by liquids with a wide range of surface tensions correlates with the length and degree of fluorination of the organosilane (with a few exceptions in the case of methyl trichlorosilane- treated paper), and with the roughness of the paper. RF paper maintains the high permeability to gases and mechanical flexibility of the untreated paper, and can be folded into functional shapes (e.g., microtiter plates and liquid-filled gas sensors). When impregnated with a perfluorinated oil, RF paper forms a "slippery" surface (paper slippery liquid-infused porous surface, or "paper SLIPS") capable of repelling liquids with surface tensions as low as 15 mN m-1. The foldability of the paper SLIPS allows the fabrication of channels and flow switches to guide the transport of liquid droplets.
KW - hydrophobic papers
KW - omniphobic papers
KW - origami
KW - paper SLIPS
KW - SLIPS
UR - http://www.scopus.com/inward/record.url?scp=84891560606&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84891560606&partnerID=8YFLogxK
U2 - 10.1002/adfm.201300780
DO - 10.1002/adfm.201300780
M3 - Article
AN - SCOPUS:84891560606
VL - 24
SP - 60
EP - 70
JO - Advanced Functional Materials
JF - Advanced Functional Materials
SN - 1616-301X
IS - 1
ER -