One-dimensional cyanide-bridged MnIIIWvbimetallic complexes: Metamagnetism, spontaneous resolution, and slow magnetic relaxation

Seok Woo Chol, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Hyoung Chan Kim, Hyosug Lee, Beong Ki Cho, Chang Seop Hong

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

The reaction of [W(CN)6(bpy)]- with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral Induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetlsm (1) to slow magnetic relaxation (2).

Original languageEnglish
Pages (from-to)9066-9068
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number19
DOIs
Publication statusPublished - 2009 Oct 14

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Metamagnetism
Magnetic relaxation
Schiff Bases
magnetic relaxation
Cyanides
cyanides
imines
chelates
Conformations
induction
Modulation
modulation
rings

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

One-dimensional cyanide-bridged MnIIIWvbimetallic complexes : Metamagnetism, spontaneous resolution, and slow magnetic relaxation. / Chol, Seok Woo; Ryu, Dae Won; Lee, Jin Wuk; Yoon, Jung Hee; Kim, Hyoung Chan; Lee, Hyosug; Cho, Beong Ki; Hong, Chang Seop.

In: Inorganic Chemistry, Vol. 48, No. 19, 14.10.2009, p. 9066-9068.

Research output: Contribution to journalArticle

Chol, Seok Woo ; Ryu, Dae Won ; Lee, Jin Wuk ; Yoon, Jung Hee ; Kim, Hyoung Chan ; Lee, Hyosug ; Cho, Beong Ki ; Hong, Chang Seop. / One-dimensional cyanide-bridged MnIIIWvbimetallic complexes : Metamagnetism, spontaneous resolution, and slow magnetic relaxation. In: Inorganic Chemistry. 2009 ; Vol. 48, No. 19. pp. 9066-9068.
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