One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

Young Sin You, Dohyeon Kim, Youngkyu Do, Sang Jun Oh, Chang Seop Hong

Research output: Contribution to journalArticle

73 Citations (Scopus)

Abstract

A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)8 3- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.

Original languageEnglish
Pages (from-to)6899-6901
Number of pages3
JournalInorganic Chemistry
Volume43
Issue number22
DOIs
Publication statusPublished - 2004 Nov 1

Fingerprint

Ladders
ladders
assembly
cyanides
assembling
interactions
Cyanides
ions
Ions
cyclam

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure. / You, Young Sin; Kim, Dohyeon; Do, Youngkyu; Oh, Sang Jun; Hong, Chang Seop.

In: Inorganic Chemistry, Vol. 43, No. 22, 01.11.2004, p. 6899-6901.

Research output: Contribution to journalArticle

You, Young Sin ; Kim, Dohyeon ; Do, Youngkyu ; Oh, Sang Jun ; Hong, Chang Seop. / One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure. In: Inorganic Chemistry. 2004 ; Vol. 43, No. 22. pp. 6899-6901.
@article{3ea1c42d1c3449efab6ba61bf0143010,
title = "One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure",
abstract = "A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)8 3- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.",
author = "You, {Young Sin} and Dohyeon Kim and Youngkyu Do and Oh, {Sang Jun} and Hong, {Chang Seop}",
year = "2004",
month = "11",
day = "1",
doi = "10.1021/ic048856i",
language = "English",
volume = "43",
pages = "6899--6901",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "22",

}

TY - JOUR

T1 - One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

AU - You, Young Sin

AU - Kim, Dohyeon

AU - Do, Youngkyu

AU - Oh, Sang Jun

AU - Hong, Chang Seop

PY - 2004/11/1

Y1 - 2004/11/1

N2 - A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)8 3- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.

AB - A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)8 3- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.

UR - http://www.scopus.com/inward/record.url?scp=7444264768&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=7444264768&partnerID=8YFLogxK

U2 - 10.1021/ic048856i

DO - 10.1021/ic048856i

M3 - Article

VL - 43

SP - 6899

EP - 6901

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 22

ER -