One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

Young Sin You; Dohyeon Kim; Youngkyu Do; Sang Jun Oh; Chang Seop Hong

doi:10.1021/ic048856i

One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

Young Sin You, Dohyeon Kim, Youngkyu Do, Sang Jun Oh, Chang Seop Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]₃[Mo(CN)₈]₂· 5H₂O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)₈^3- and Cu(cyclam)²⁺ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu₃Mo₂ unit (J_p = 3.88 cm^-1). Interunit ferromagnetic interactions (J_c = -0.03 cm^-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm^-1) resulting from interchain interactions are obtained.

Original language	English
Pages (from-to)	6899-6901
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	22
DOIs	https://doi.org/10.1021/ic048856i
Publication status	Published - 2004 Nov 1

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic048856i

Cite this

@article{3ea1c42d1c3449efab6ba61bf0143010,

title = "One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure",

abstract = "A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)83- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.",

author = "You, {Young Sin} and Dohyeon Kim and Youngkyu Do and Oh, {Sang Jun} and Hong, {Chang Seop}",

year = "2004",

month = nov,

day = "1",

doi = "10.1021/ic048856i",

language = "English",

volume = "43",

pages = "6899--6901",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

AU - You, Young Sin

AU - Kim, Dohyeon

AU - Do, Youngkyu

AU - Oh, Sang Jun

AU - Hong, Chang Seop

PY - 2004/11/1

Y1 - 2004/11/1

N2 - A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)83- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.

AB - A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)83- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.

UR - http://www.scopus.com/inward/record.url?scp=7444264768&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=7444264768&partnerID=8YFLogxK

U2 - 10.1021/ic048856i

DO - 10.1021/ic048856i

M3 - Article

C2 - 15500327

AN - SCOPUS:7444264768

SN - 0020-1669

VL - 43

SP - 6899

EP - 6901

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this