One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure

Young Sin You, Dohyeon Kim, Youngkyu Do, Sang Jun Oh, Chang Seop Hong

Research output: Contribution to journalArticle

73 Citations (Scopus)

Abstract

A new type of one-dimensional cyanide-bridged Cu(II)-Mo(V) bimetallic assembly, [Cu(cyclam)]3[Mo(CN)8]2· 5H2O (cyclam = 1,4,8,11-tetraazacyclotetradecane), was prepared by self-assembling Mo(CN)83- and Cu(cyclam)2+ ions in a 2:3 stoichiometric ratio. The overall molecular view is delineated as a novel rope-ladder chain structure. It displays a dominant ferromagnetic behavior within a pentanuclear Cu3Mo2 unit (Jp = 3.88 cm-1). Interunit ferromagnetic interactions (Jc = -0.03 cm-1) through a longer magnetic pathway of Cu-Mo and weak antiferromagnetic couplings (zJ′ = -0.46 cm-1) resulting from interchain interactions are obtained.

Original languageEnglish
Pages (from-to)6899-6901
Number of pages3
JournalInorganic Chemistry
Volume43
Issue number22
DOIs
Publication statusPublished - 2004 Nov 1

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'One-dimensional octacyanomolybdate-based Cu(II)-Mo(V) bimetallic assembly with a novel rope-ladder chain structure'. Together they form a unique fingerprint.

  • Cite this