One-step polymerization of aniline and its conducting blends in organic system

Bo Hyun Lee; Tae Young Kim; Jong Eun Kim; Kwang S. Suh

One-step polymerization of aniline and its conducting blends in organic system

Bo Hyun Lee, Tae Young Kim, Jong Eun Kim, Kwang S. Suh

Department of Materials Science and Engineering

Research output: Contribution to conference › Paper › peer-review

2 Citations (Scopus)

Abstract

Stable polyaniline-dodecylbenzenesulfonic acid (PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. The polymerization of aniline was carried out in an emulsion comprising water, toluene and DBSA acting both as a surfactant and a dopant for PANI. After the proper washing process was performed, the conductivity of obtained PANI-DBSA complex increased with increase APS/Aniline molar ratio and DBSA/Aniline molar ratio. The UV-Vis absorption spectra of PANI-DBSA complex also supported these results. PANI-DBSA/polymer (polystyrene and styrene-butadiene copolymer) blends were prepared by mixing PANI-DBSA complex with polymer in toluene. These blends exhibited relatively high conductivity of 10^-2 S/cm at a low PANI-DBSA content (1-5 wt.%).

Original language	English
Pages	479-482
Number of pages	4
Publication status	Published - 2001
Event	Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems - Himeji, Japan Duration: 2001 Nov 19 → 2001 Nov 22

Other

Other	Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems
Country/Territory	Japan
City	Himeji
Period	01/11/19 → 01/11/22

ASJC Scopus subject areas

Engineering(all)
Materials Science(all)

Cite this

Lee, B. H., Kim, T. Y., Kim, J. E., & Suh, K. S. (2001). One-step polymerization of aniline and its conducting blends in organic system. 479-482. Paper presented at Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems, Himeji, Japan.

One-step polymerization of aniline and its conducting blends in organic system. / Lee, Bo Hyun; Kim, Tae Young; Kim, Jong Eun; Suh, Kwang S.

2001. 479-482 Paper presented at Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems, Himeji, Japan.

Research output: Contribution to conference › Paper › peer-review

Lee, BH, Kim, TY, Kim, JE & Suh, KS 2001, 'One-step polymerization of aniline and its conducting blends in organic system', Paper presented at Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems, Himeji, Japan, 01/11/19 - 01/11/22 pp. 479-482.

Lee BH, Kim TY, Kim JE, Suh KS. One-step polymerization of aniline and its conducting blends in organic system. 2001. Paper presented at Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems, Himeji, Japan.

Lee, Bo Hyun ; Kim, Tae Young ; Kim, Jong Eun ; Suh, Kwang S. / One-step polymerization of aniline and its conducting blends in organic system. Paper presented at Proceedings of 2001 International Symp. on Electrical Insulating Materials (ISEIM 2001) / 2001 Asian Conf. on Electrical Insulation Diagnosis (ACEID 2001) / 33rd Symp. on Electrical and Electronic Insulating Materials and Applications in Systems, Himeji, Japan.4 p.

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abstract = "Stable polyaniline-dodecylbenzenesulfonic acid (PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. The polymerization of aniline was carried out in an emulsion comprising water, toluene and DBSA acting both as a surfactant and a dopant for PANI. After the proper washing process was performed, the conductivity of obtained PANI-DBSA complex increased with increase APS/Aniline molar ratio and DBSA/Aniline molar ratio. The UV-Vis absorption spectra of PANI-DBSA complex also supported these results. PANI-DBSA/polymer (polystyrene and styrene-butadiene copolymer) blends were prepared by mixing PANI-DBSA complex with polymer in toluene. These blends exhibited relatively high conductivity of 10-2 S/cm at a low PANI-DBSA content (1-5 wt.%).",

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N2 - Stable polyaniline-dodecylbenzenesulfonic acid (PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. The polymerization of aniline was carried out in an emulsion comprising water, toluene and DBSA acting both as a surfactant and a dopant for PANI. After the proper washing process was performed, the conductivity of obtained PANI-DBSA complex increased with increase APS/Aniline molar ratio and DBSA/Aniline molar ratio. The UV-Vis absorption spectra of PANI-DBSA complex also supported these results. PANI-DBSA/polymer (polystyrene and styrene-butadiene copolymer) blends were prepared by mixing PANI-DBSA complex with polymer in toluene. These blends exhibited relatively high conductivity of 10-2 S/cm at a low PANI-DBSA content (1-5 wt.%).

AB - Stable polyaniline-dodecylbenzenesulfonic acid (PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. The polymerization of aniline was carried out in an emulsion comprising water, toluene and DBSA acting both as a surfactant and a dopant for PANI. After the proper washing process was performed, the conductivity of obtained PANI-DBSA complex increased with increase APS/Aniline molar ratio and DBSA/Aniline molar ratio. The UV-Vis absorption spectra of PANI-DBSA complex also supported these results. PANI-DBSA/polymer (polystyrene and styrene-butadiene copolymer) blends were prepared by mixing PANI-DBSA complex with polymer in toluene. These blends exhibited relatively high conductivity of 10-2 S/cm at a low PANI-DBSA content (1-5 wt.%).

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One-step polymerization of aniline and its conducting blends in organic system

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