One step synthesis of Au nanoparticle-cyclized polyacrylonitrile composite films and their use in organic nano-floating gate memory applications

Se Phin Cho, Sukjae Jang, Hae Na Jo, Sang A. Lee, Sukang Bae, Sang Hyun Lee, Junyeon Hwang, Han Ik Joh, Gunuk Wang, Tae Wook Kim

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In this study, we synthesized Au nanoparticles (AuNPs) in polyacrylonitrile (PAN) thin films using a simple annealing process in the solid phase. The synthetic conditions were systematically controlled and optimized by varying the concentration of the Au salt solution and the annealing temperature. X-ray photoelectron spectroscopy (XPS) confirmed their chemical state, and transmission electron microscopy (TEM) verified the successful synthesis, size, and density of AuNPs. Au nanoparticles were generated from the thermal decomposition of the Au salt and stabilized during the cyclization of the PAN matrix. For actual device applications, previous synthetic techniques have required the synthesis of AuNPs in a liquid phase and an additional process to form the thin film layer, such as spin-coating, dip-coating, Langmuir-Blodgett, or high vacuum deposition. In contrast, our one-step synthesis could produce gold nanoparticles from the Au salt contained in a solid matrix with an easy heat treatment. The PAN:AuNPs composite was used as the charge trap layer of an organic nano-floating gate memory (ONFGM). The memory devices exhibited a high on/off ratio (over 106), large hysteresis windows (76.7 V), and a stable endurance performance (>3000 cycles), indicating that our stabilized PAN:AuNPs composite film is a potential charge trap medium for next generation organic nano-floating gate memory transistors.

Original languageEnglish
Pages (from-to)1511-1516
Number of pages6
JournalJournal of Materials Chemistry C
Volume4
Issue number7
DOIs
Publication statusPublished - 2016 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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