Organic donor-σ-acceptor molecules based-on 5,5′-(9,10-bis((4- hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2- hexylthiophene)

Jicheol Shin; Tae Wan Lee; Nam Su Kang; Kyung Hwan Kim; Jae Min Hong; Dong Hoon Choi

doi:10.1016/j.synthmet.2012.05.010

Organic donor-σ-acceptor molecules based-on 5,5′-(9,10-bis((4- hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2- hexylthiophene)

Jicheol Shin, Tae Wan Lee, Nam Su Kang, Kyung Hwan Kim, Jae Min Hong, Dong Hoon Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

New donor-σ-acceptor (D-σ-A) molecules of (HAT)-n(PCBM) (where n = 1 and 2; PCBM refers to [6,6]-phenyl C61-butyric acid methyl ester and HAT refers to 5,5′-(9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl) bis(ethyne-2,1-diyl)bis(2-hexylthiophene)) were successfully synthesized for studying the intermolecular association behavior and their possible applications of these molecules to photovoltaic (PV) devices. In PV devices, (HAT)-n(PCBM) gave a reasonably high power conversion efficiency (PCE) of 0.18-0.44% with an open circuit voltage (V _oc) ranging from 0.42 to 0.51 V without adding extra amount of PCBM.

Original language	English
Pages (from-to)	1335-1342
Number of pages	8
Journal	Synthetic Metals
Volume	162
Issue number	15-16
DOIs	https://doi.org/10.1016/j.synthmet.2012.05.010
Publication status	Published - 2012 Sept

Keywords

Anthracene
Conjugated molecules
Donor-σ-acceptor
PCBM
Photovoltaic cell
Semiconductor

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.synthmet.2012.05.010

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@article{10383cf15d944f3eba11681e57252e13,

title = "Organic donor-σ-acceptor molecules based-on 5,5′-(9,10-bis((4- hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2- hexylthiophene)",

abstract = "New donor-σ-acceptor (D-σ-A) molecules of (HAT)-n(PCBM) (where n = 1 and 2; PCBM refers to [6,6]-phenyl C61-butyric acid methyl ester and HAT refers to 5,5′-(9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl) bis(ethyne-2,1-diyl)bis(2-hexylthiophene)) were successfully synthesized for studying the intermolecular association behavior and their possible applications of these molecules to photovoltaic (PV) devices. In PV devices, (HAT)-n(PCBM) gave a reasonably high power conversion efficiency (PCE) of 0.18-0.44% with an open circuit voltage (V oc) ranging from 0.42 to 0.51 V without adding extra amount of PCBM.",

keywords = "Anthracene, Conjugated molecules, Donor-σ-acceptor, PCBM, Photovoltaic cell, Semiconductor",

author = "Jicheol Shin and Lee, {Tae Wan} and Kang, {Nam Su} and Kim, {Kyung Hwan} and Hong, {Jae Min} and Choi, {Dong Hoon}",

note = "Funding Information: This research was supported by National Research Foundation of Korea (NRF 2012008797) and by Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (NRF 20120005860). D.H. Choi particularly thanks for the support by 21st century Frontier Research Program (F0004011201134100200051196F0004000201134, 2011).",

year = "2012",

month = sep,

doi = "10.1016/j.synthmet.2012.05.010",

language = "English",

volume = "162",

pages = "1335--1342",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "15-16",

}

TY - JOUR

T1 - Organic donor-σ-acceptor molecules based-on 5,5′-(9,10-bis((4- hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2- hexylthiophene)

AU - Shin, Jicheol

AU - Lee, Tae Wan

AU - Kang, Nam Su

AU - Kim, Kyung Hwan

AU - Hong, Jae Min

AU - Choi, Dong Hoon

N1 - Funding Information: This research was supported by National Research Foundation of Korea (NRF 2012008797) and by Priority Research Centers Program through the NRF funded by the Ministry of Education, Science and Technology (NRF 20120005860). D.H. Choi particularly thanks for the support by 21st century Frontier Research Program (F0004011201134100200051196F0004000201134, 2011).

PY - 2012/9

Y1 - 2012/9

N2 - New donor-σ-acceptor (D-σ-A) molecules of (HAT)-n(PCBM) (where n = 1 and 2; PCBM refers to [6,6]-phenyl C61-butyric acid methyl ester and HAT refers to 5,5′-(9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl) bis(ethyne-2,1-diyl)bis(2-hexylthiophene)) were successfully synthesized for studying the intermolecular association behavior and their possible applications of these molecules to photovoltaic (PV) devices. In PV devices, (HAT)-n(PCBM) gave a reasonably high power conversion efficiency (PCE) of 0.18-0.44% with an open circuit voltage (V oc) ranging from 0.42 to 0.51 V without adding extra amount of PCBM.

AB - New donor-σ-acceptor (D-σ-A) molecules of (HAT)-n(PCBM) (where n = 1 and 2; PCBM refers to [6,6]-phenyl C61-butyric acid methyl ester and HAT refers to 5,5′-(9,10-bis((4-hexylphenyl)ethynyl)anthracene-2,6-diyl) bis(ethyne-2,1-diyl)bis(2-hexylthiophene)) were successfully synthesized for studying the intermolecular association behavior and their possible applications of these molecules to photovoltaic (PV) devices. In PV devices, (HAT)-n(PCBM) gave a reasonably high power conversion efficiency (PCE) of 0.18-0.44% with an open circuit voltage (V oc) ranging from 0.42 to 0.51 V without adding extra amount of PCBM.

KW - Anthracene

KW - Conjugated molecules

KW - Donor-σ-acceptor

KW - PCBM

KW - Photovoltaic cell

KW - Semiconductor

UR - http://www.scopus.com/inward/record.url?scp=84863197424&partnerID=8YFLogxK

U2 - 10.1016/j.synthmet.2012.05.010

DO - 10.1016/j.synthmet.2012.05.010

M3 - Article

AN - SCOPUS:84863197424

SN - 0379-6779

VL - 162

SP - 1335

EP - 1342

JO - Synthetic Metals

JF - Synthetic Metals

IS - 15-16

ER -

Organic donor-σ-acceptor molecules based-on 5,5′-(9,10-bis((4- hexylphenyl)ethynyl)anthracene-2,6-diyl)bis(ethyne-2,1-diyl)bis(2- hexylthiophene)

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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