Organic photovoltaics interdigitated on the molecular scale

Alex B F Martinson, Aaron M. Massari, Suk Joong Lee, Richard W. Gurney, Kathryn E. Splan, Joseph T. Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Phosphonated porphyrin frameworks that are porous to an electron-accepting perylenediimide are systematically interdigitated with a phosphonated form of the diimide to form bulk heterojunctions. When employed in photovoltaics, these molecularly interlaced heterojunctions provide large junction areas while retaining the phase connectivity of traditional bilayer heterojunctions. Zirconium phosphonate linkages facilitate layer-by-layer chromophore assembly from solution under ambient conditions. The dependence of photovoltaic performance on heterojunction architecture is investigated.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume153
Issue number3
DOIs
Publication statusPublished - 2006 Feb 13
Externally publishedYes

Fingerprint

Heterojunctions
heterojunctions
Organophosphonates
Porphyrins
Chromophores
retaining
Zirconium
linkages
porphyrins
chromophores
assembly
Electrons
electrons

ASJC Scopus subject areas

  • Electrochemistry
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

Martinson, A. B. F., Massari, A. M., Lee, S. J., Gurney, R. W., Splan, K. E., Hupp, J. T., & Nguyen, S. T. (2006). Organic photovoltaics interdigitated on the molecular scale. Journal of the Electrochemical Society, 153(3). https://doi.org/10.1149/1.2165788

Organic photovoltaics interdigitated on the molecular scale. / Martinson, Alex B F; Massari, Aaron M.; Lee, Suk Joong; Gurney, Richard W.; Splan, Kathryn E.; Hupp, Joseph T.; Nguyen, Sonbinh T.

In: Journal of the Electrochemical Society, Vol. 153, No. 3, 13.02.2006.

Research output: Contribution to journalArticle

Martinson, ABF, Massari, AM, Lee, SJ, Gurney, RW, Splan, KE, Hupp, JT & Nguyen, ST 2006, 'Organic photovoltaics interdigitated on the molecular scale', Journal of the Electrochemical Society, vol. 153, no. 3. https://doi.org/10.1149/1.2165788
Martinson, Alex B F ; Massari, Aaron M. ; Lee, Suk Joong ; Gurney, Richard W. ; Splan, Kathryn E. ; Hupp, Joseph T. ; Nguyen, Sonbinh T. / Organic photovoltaics interdigitated on the molecular scale. In: Journal of the Electrochemical Society. 2006 ; Vol. 153, No. 3.
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