Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions

Kwangyeol Lee; Yong Ho Kim; Soo Bong Han; Hongkyu Kang; Soyoung Park; Won Seok Seo; Joon T. Park; Bongsoo Kim; Sukbok Chang

doi:10.1021/ja034137b

Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions

Kwangyeol Lee, Yong Ho Kim, Soo Bong Han, Hongkyu Kang, Soyoung Park, Won Seok Seo, Joon T. Park, Bongsoo Kim, Sukbok Chang

Research output: Contribution to journal › Article › peer-review

92 Citations (Scopus)

Abstract

A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os₃(CO)₁₂ within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.

Original language	English
Pages (from-to)	6844-6845
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	23
DOIs	https://doi.org/10.1021/ja034137b
Publication status	Published - 2003 Jun 11
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja034137b

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abstract = "A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os3(CO)12 within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.",

author = "Kwangyeol Lee and Kim, {Yong Ho} and Han, {Soo Bong} and Hongkyu Kang and Soyoung Park and Seo, {Won Seok} and Park, {Joon T.} and Bongsoo Kim and Sukbok Chang",

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T2 - Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions

AU - Lee, Kwangyeol

AU - Kim, Yong Ho

AU - Han, Soo Bong

AU - Kang, Hongkyu

AU - Park, Soyoung

AU - Seo, Won Seok

AU - Park, Joon T.

AU - Kim, Bongsoo

AU - Chang, Sukbok

PY - 2003/6/11

Y1 - 2003/6/11

N2 - A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os3(CO)12 within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.

AB - A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os3(CO)12 within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.

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ER -

Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions

Abstract

ASJC Scopus subject areas

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