Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions

Kwangyeol Lee; Yong Ho Kim; Soo Bong Han; Hongkyu Kang; Soyoung Park; Won Seok Seo; Joon T. Park; Bongsoo Kim; Sukbok Chang

doi:10.1021/ja034137b

Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions

Kwangyeol Lee, Yong Ho Kim, Soo Bong Han, Hongkyu Kang, Soyoung Park, Won Seok Seo, Joon T. Park, Bongsoo Kim, Sukbok Chang

Department of Chemistry

Research output: Contribution to journal › Article

80 Citations (Scopus)

Abstract

A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os₃(CO)₁₂ within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.

Original language	English
Pages (from-to)	6844-6845
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	23
DOIs	https://doi.org/10.1021/ja034137b
Publication status	Published - 2003 Jun 11

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja034137b

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Lee, K., Kim, Y. H., Han, S. B., Kang, H., Park, S., Seo, W. S., Park, J. T., Kim, B., & Chang, S. (2003). Osmium replica of mesoporous silicate MCM-48: Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions. Journal of the American Chemical Society, 125(23), 6844-6845. https://doi.org/10.1021/ja034137b

Osmium replica of mesoporous silicate MCM-48 : Efficient and reusable catalyst for oxidative cleavage and dihydroxylation reactions. / Lee, Kwangyeol; Kim, Yong Ho; Han, Soo Bong; Kang, Hongkyu; Park, Soyoung; Seo, Won Seok; Park, Joon T.; Kim, Bongsoo; Chang, Sukbok.

In: Journal of the American Chemical Society, Vol. 125, No. 23, 11.06.2003, p. 6844-6845.

Research output: Contribution to journal › Article

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abstract = "A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os3(CO)12 within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.",

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