[Os3(CO)6(PMe3)3] (μ3222-C 60)[Re3(μ-H)3(CO)9]: A fullerene[60] coordinated to two different trinuclear clusters

Bo Keun Park, Chang Yeon Lee, Jaehoon Jung, Jung Hak Lim, Young Kyu Han, Chang Seop Hong, Joon T. Park

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

(Chemical Equation Presented) A buckyball sandwich: The depicted reaction produces cis-1 and cis-2 (see picture), in which the fullerene is sandwiched between two different clusters. Variable-temperature 1H NMR spectra reveal that cis-1 and cis-2 are interconvertible and cis-2 exists as two isomers.

Original languageEnglish
Pages (from-to)1436-1439
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number9
DOIs
Publication statusPublished - 2007

Keywords

  • Cluster compounds
  • Density functional calculations
  • Fullerenes
  • Osmium
  • Rhenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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