Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation

Sung Kwan Kim, Won Sik Han, Tae Jin Kim, Tae Young Kim, Suk Woo Nam, Mariusz Mitoraj, Lukasz Piekoś, Artur Michalak, Son Jong Hwang, Sang Ook Kang

Research output: Contribution to journalArticle

143 Citations (Scopus)

Abstract

Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

Original languageEnglish
Pages (from-to)9954-9955
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number29
DOIs
Publication statusPublished - 2010 Jul 28

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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    Kim, S. K., Han, W. S., Kim, T. J., Kim, T. Y., Nam, S. W., Mitoraj, M., Piekoś, L., Michalak, A., Hwang, S. J., & Kang, S. O. (2010). Palladium catalysts for dehydrogenation of ammonia borane with preferential b-h activation. Journal of the American Chemical Society, 132(29), 9954-9955. https://doi.org/10.1021/ja101685u