PCR-like cascade reactions in the context of an allosteric enzyme mimic

Jae Yoon Hyo; Chad A. Mirkin

doi:10.1021/ja804076q

PCR-like cascade reactions in the context of an allosteric enzyme mimic

Jae Yoon Hyo, Chad A. Mirkin

Research output: Contribution to journal › Article › peer-review

95 Citations (Scopus)

Abstract

A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.

Original language	English
Pages (from-to)	11590-11591
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	35
DOIs	https://doi.org/10.1021/ja804076q
Publication status	Published - 2008 Sep 3
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja804076q

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abstract = "A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.",

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PCR-like cascade reactions in the context of an allosteric enzyme mimic

Abstract

ASJC Scopus subject areas

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