Abstract
A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 11590-11591 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 130 |
| Issue number | 35 |
| DOIs | |
| Publication status | Published - 2008 Sep 3 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
PCR-like cascade reactions in the context of an allosteric enzyme mimic. / Yoon, Hyo Jae; Mirkin, Chad A.
In: Journal of the American Chemical Society, Vol. 130, No. 35, 03.09.2008, p. 11590-11591.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - PCR-like cascade reactions in the context of an allosteric enzyme mimic
AU - Yoon, Hyo Jae
AU - Mirkin, Chad A.
PY - 2008/9/3
Y1 - 2008/9/3
N2 - A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.
AB - A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.
UR - http://www.scopus.com/inward/record.url?scp=51349144669&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=51349144669&partnerID=8YFLogxK
U2 - 10.1021/ja804076q
DO - 10.1021/ja804076q
M3 - Article
C2 - 18681433
AN - SCOPUS:51349144669
VL - 130
SP - 11590
EP - 11591
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 35
ER -