Performance and properties of anodes reinforced with metal oxide nanoparticles for molten carbonate fuel cells

Grazia Accardo, Domenico Frattini, Sung Pil Yoon, Hyung Chul Ham, SukWoo Nam

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Development of electrode materials for molten carbonate fuel cells is a fundamental issue as a balance between mechanical and electrochemical properties is required due to the particular operating environments of these cells. As concern the anode, a viable strategy is to use nano-reinforced particles during electrodes' fabrication. Candidate nanomaterials comprise, but are not limited to, ZrO2, CeO2, TiO2, Ti, Mg, Al, etc. This work deals with the characterization and test of two different types of hard oxide nanoparticles as reinforce for NiAl-based anodes in molten carbonate fuel cells. Nano ceria and nano zirconia are compared each other and single cell test performances are presented. Compared to literature, the use of hard metal oxide nanoparticles allows good performance and promising perspectives with respect to the use a third alloying metal. However, nano zirconia performed slightly better than nano ceria as polarization and power curves are higher even if nano ceria has the highest mechanical properties. This means that the choice of nanoparticles to obtain improved anodes performance and properties is not trivial and a trade-off between relevant properties plays a key role.

Original languageEnglish
Pages (from-to)52-60
Number of pages9
JournalJournal of Power Sources
Volume370
DOIs
Publication statusPublished - 2017 Dec 1
Externally publishedYes

Fingerprint

molten carbonate fuel cells
Molten carbonate fuel cells (MCFC)
Cerium compounds
Oxides
metal oxides
Anodes
anodes
Metals
Nanoparticles
zirconium oxides
Zirconia
nanoparticles
mechanical properties
Mechanical properties
Electrodes
performance tests
electrode materials
cells
Electrochemical properties
Alloying

Keywords

  • Anode
  • Cell test
  • Characterization
  • Nanoparticle
  • Performance

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

Performance and properties of anodes reinforced with metal oxide nanoparticles for molten carbonate fuel cells. / Accardo, Grazia; Frattini, Domenico; Yoon, Sung Pil; Ham, Hyung Chul; Nam, SukWoo.

In: Journal of Power Sources, Vol. 370, 01.12.2017, p. 52-60.

Research output: Contribution to journalArticle

Accardo, Grazia ; Frattini, Domenico ; Yoon, Sung Pil ; Ham, Hyung Chul ; Nam, SukWoo. / Performance and properties of anodes reinforced with metal oxide nanoparticles for molten carbonate fuel cells. In: Journal of Power Sources. 2017 ; Vol. 370. pp. 52-60.
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