Phosphorescent, green-emitting Ir(III) complexes with carbazolyl-substituted 2-phenylpyridine ligands: Effect of binding mode of the carbazole group on photoluminescence and electrophosphorescence

Min Ju Cho, Jung Il Jin, Dong Hoon Choi, Young Min Kim, Young Wook Park, Byeong Kwon Ju

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The ligands, 9-((6-phenylpyridin-3-yl)methyl)-9H-carbazole and 9-(4-(pyridin-2-yl)benzyl)-9H-carbazole were synthesized by attaching a carbazolyl group to the pyridine and phenyl rings of 2-phenylpyridine, respectively. Ir(III) complexes were prepared by a simple procedure and the solubility of the novel complexes was significantly better than that of the conventional, green-emitting conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). The Ir(III) complexes were used to prepare electrophosphorescent polymer light-emitting devices. The device comprising 10% of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) exhibited an external quantum efficiency of 7.88%, luminous efficiency of 23.01 cd/A, and maximum brightness of 32,640 cd/m2. The color of the emissions of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) was similar to that of conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). This work shows that integration of a rigid hole-transporting carbazole and phosphorescent complex in one molecule provides a new route to highly efficient, solution-processable complexes for electrophosphorescent applications.

Original languageEnglish
Pages (from-to)218-224
Number of pages7
JournalDyes and Pigments
Volume83
Issue number2
DOIs
Publication statusPublished - 2009 Nov 1

Fingerprint

Iridium
Photoluminescence
Ligands
Quantum efficiency
2-phenylpyridine
carbazole
Luminance
Polymers
Solubility
Pyridine
Color
Molecules

Keywords

  • Carbazole
  • Iridium(III) complex
  • Phosphorescence
  • Photoluminescence
  • Solubility
  • Triplet energy transfer

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Process Chemistry and Technology

Cite this

@article{8f347d5e5bce4639920693e8b11b3f0d,
title = "Phosphorescent, green-emitting Ir(III) complexes with carbazolyl-substituted 2-phenylpyridine ligands: Effect of binding mode of the carbazole group on photoluminescence and electrophosphorescence",
abstract = "The ligands, 9-((6-phenylpyridin-3-yl)methyl)-9H-carbazole and 9-(4-(pyridin-2-yl)benzyl)-9H-carbazole were synthesized by attaching a carbazolyl group to the pyridine and phenyl rings of 2-phenylpyridine, respectively. Ir(III) complexes were prepared by a simple procedure and the solubility of the novel complexes was significantly better than that of the conventional, green-emitting conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). The Ir(III) complexes were used to prepare electrophosphorescent polymer light-emitting devices. The device comprising 10{\%} of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) exhibited an external quantum efficiency of 7.88{\%}, luminous efficiency of 23.01 cd/A, and maximum brightness of 32,640 cd/m2. The color of the emissions of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) was similar to that of conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). This work shows that integration of a rigid hole-transporting carbazole and phosphorescent complex in one molecule provides a new route to highly efficient, solution-processable complexes for electrophosphorescent applications.",
keywords = "Carbazole, Iridium(III) complex, Phosphorescence, Photoluminescence, Solubility, Triplet energy transfer",
author = "Cho, {Min Ju} and Jin, {Jung Il} and Choi, {Dong Hoon} and Kim, {Young Min} and Park, {Young Wook} and Ju, {Byeong Kwon}",
year = "2009",
month = "11",
day = "1",
doi = "10.1016/j.dyepig.2009.04.010",
language = "English",
volume = "83",
pages = "218--224",
journal = "Dyes and Pigments",
issn = "0143-7208",
publisher = "Elsevier BV",
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}

TY - JOUR

T1 - Phosphorescent, green-emitting Ir(III) complexes with carbazolyl-substituted 2-phenylpyridine ligands

T2 - Effect of binding mode of the carbazole group on photoluminescence and electrophosphorescence

AU - Cho, Min Ju

AU - Jin, Jung Il

AU - Choi, Dong Hoon

AU - Kim, Young Min

AU - Park, Young Wook

AU - Ju, Byeong Kwon

PY - 2009/11/1

Y1 - 2009/11/1

N2 - The ligands, 9-((6-phenylpyridin-3-yl)methyl)-9H-carbazole and 9-(4-(pyridin-2-yl)benzyl)-9H-carbazole were synthesized by attaching a carbazolyl group to the pyridine and phenyl rings of 2-phenylpyridine, respectively. Ir(III) complexes were prepared by a simple procedure and the solubility of the novel complexes was significantly better than that of the conventional, green-emitting conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). The Ir(III) complexes were used to prepare electrophosphorescent polymer light-emitting devices. The device comprising 10% of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) exhibited an external quantum efficiency of 7.88%, luminous efficiency of 23.01 cd/A, and maximum brightness of 32,640 cd/m2. The color of the emissions of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) was similar to that of conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). This work shows that integration of a rigid hole-transporting carbazole and phosphorescent complex in one molecule provides a new route to highly efficient, solution-processable complexes for electrophosphorescent applications.

AB - The ligands, 9-((6-phenylpyridin-3-yl)methyl)-9H-carbazole and 9-(4-(pyridin-2-yl)benzyl)-9H-carbazole were synthesized by attaching a carbazolyl group to the pyridine and phenyl rings of 2-phenylpyridine, respectively. Ir(III) complexes were prepared by a simple procedure and the solubility of the novel complexes was significantly better than that of the conventional, green-emitting conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). The Ir(III) complexes were used to prepare electrophosphorescent polymer light-emitting devices. The device comprising 10% of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) exhibited an external quantum efficiency of 7.88%, luminous efficiency of 23.01 cd/A, and maximum brightness of 32,640 cd/m2. The color of the emissions of fac-tris(2-(4′-((9H-carbazol-9-yl)methyl)phenyl)pyridinato-C2,N)iridium(III) was similar to that of conventional fac-tris(2-phenylpyridinato-C2,N)iridium(III). This work shows that integration of a rigid hole-transporting carbazole and phosphorescent complex in one molecule provides a new route to highly efficient, solution-processable complexes for electrophosphorescent applications.

KW - Carbazole

KW - Iridium(III) complex

KW - Phosphorescence

KW - Photoluminescence

KW - Solubility

KW - Triplet energy transfer

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U2 - 10.1016/j.dyepig.2009.04.010

DO - 10.1016/j.dyepig.2009.04.010

M3 - Article

AN - SCOPUS:67649343909

VL - 83

SP - 218

EP - 224

JO - Dyes and Pigments

JF - Dyes and Pigments

SN - 0143-7208

IS - 2

ER -