Abstract
Sulfonated poly(fluorinated arylene ether)s (SDF-F)/poly[(N-vinylimidazole) -co-(3-methacryloxypropyl-trimethoxysilane)] (poly(VI-co-MPS))/ poly(tetrafluoroethylene) (PTFE) is prepared for a high temperature proton exchange membrane fuel cell (PEMFC). The reaction of the membrane with phosphoric acid forms silicate phosphor, as a chemically bound proton carrier, in the membrane. Thus-formed silicate phosphor, nitrogen in the imidazole ring, and physically bound phosphoric acid act as proton carriers in the membrane. The physico-chemical and electrochemical properties of the membrane are investigated by various analytical tools. The phosphoric acid uptake and proton conductivity of the SDF-F/poly(VI-co-MPS)/PTFE membrane are higher than those of SDF-F/PVI/PTFE. The power densities of cells with SDF-F/poly(VI-co-MPS)/PTFE membranes at 0.6 V are 286, 302, and 320 mW cm-2 at 150, 170, and 190 °C, respectively. Overall, the SDFF/ poly(VI-co-MPS)/PTFE membrane is one of the candidates for anhydrous HT-PEMFCs with enhanced mechanical strength and improved cell performance.
| Original language | English |
|---|---|
| Pages (from-to) | 1902-1906 |
| Number of pages | 5 |
| Journal | Bulletin of the Korean Chemical Society |
| Volume | 32 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2011 Jun 20 |
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Keywords
- Acid-doped membrane
- Anhydrous condition
- High-temperature PEMFCs
- Proton conducting membrane
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Phosphoric acid-doped SDF-F/poly(VI-co-MPS)/PTFE membrane for a high temperature proton exchange membrane fuel cell. / Lee, Jongwon; Yi, Cheol Woo; Kim, Keon.
In: Bulletin of the Korean Chemical Society, Vol. 32, No. 6, 20.06.2011, p. 1902-1906.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Phosphoric acid-doped SDF-F/poly(VI-co-MPS)/PTFE membrane for a high temperature proton exchange membrane fuel cell
AU - Lee, Jongwon
AU - Yi, Cheol Woo
AU - Kim, Keon
PY - 2011/6/20
Y1 - 2011/6/20
N2 - Sulfonated poly(fluorinated arylene ether)s (SDF-F)/poly[(N-vinylimidazole) -co-(3-methacryloxypropyl-trimethoxysilane)] (poly(VI-co-MPS))/ poly(tetrafluoroethylene) (PTFE) is prepared for a high temperature proton exchange membrane fuel cell (PEMFC). The reaction of the membrane with phosphoric acid forms silicate phosphor, as a chemically bound proton carrier, in the membrane. Thus-formed silicate phosphor, nitrogen in the imidazole ring, and physically bound phosphoric acid act as proton carriers in the membrane. The physico-chemical and electrochemical properties of the membrane are investigated by various analytical tools. The phosphoric acid uptake and proton conductivity of the SDF-F/poly(VI-co-MPS)/PTFE membrane are higher than those of SDF-F/PVI/PTFE. The power densities of cells with SDF-F/poly(VI-co-MPS)/PTFE membranes at 0.6 V are 286, 302, and 320 mW cm-2 at 150, 170, and 190 °C, respectively. Overall, the SDFF/ poly(VI-co-MPS)/PTFE membrane is one of the candidates for anhydrous HT-PEMFCs with enhanced mechanical strength and improved cell performance.
AB - Sulfonated poly(fluorinated arylene ether)s (SDF-F)/poly[(N-vinylimidazole) -co-(3-methacryloxypropyl-trimethoxysilane)] (poly(VI-co-MPS))/ poly(tetrafluoroethylene) (PTFE) is prepared for a high temperature proton exchange membrane fuel cell (PEMFC). The reaction of the membrane with phosphoric acid forms silicate phosphor, as a chemically bound proton carrier, in the membrane. Thus-formed silicate phosphor, nitrogen in the imidazole ring, and physically bound phosphoric acid act as proton carriers in the membrane. The physico-chemical and electrochemical properties of the membrane are investigated by various analytical tools. The phosphoric acid uptake and proton conductivity of the SDF-F/poly(VI-co-MPS)/PTFE membrane are higher than those of SDF-F/PVI/PTFE. The power densities of cells with SDF-F/poly(VI-co-MPS)/PTFE membranes at 0.6 V are 286, 302, and 320 mW cm-2 at 150, 170, and 190 °C, respectively. Overall, the SDFF/ poly(VI-co-MPS)/PTFE membrane is one of the candidates for anhydrous HT-PEMFCs with enhanced mechanical strength and improved cell performance.
KW - Acid-doped membrane
KW - Anhydrous condition
KW - High-temperature PEMFCs
KW - Proton conducting membrane
UR - http://www.scopus.com/inward/record.url?scp=79959384431&partnerID=8YFLogxK
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U2 - 10.5012/bkcs.2011.32.6.1902
DO - 10.5012/bkcs.2011.32.6.1902
M3 - Article
AN - SCOPUS:79959384431
VL - 32
SP - 1902
EP - 1906
JO - Bulletin of the Korean Chemical Society
JF - Bulletin of the Korean Chemical Society
SN - 0253-2964
IS - 6
ER -