Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores

Nadia Dozova; Rajesh Kumar; Tuhin Pradhan; Fabien Lacombat; Bernard Valeur; Jong Seung Kim; Pascal Plaza

doi:10.1039/c5cc06054k

Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores

Nadia Dozova, Rajesh Kumar, Tuhin Pradhan, Fabien Lacombat, Bernard Valeur, Jong Seung Kim, Pascal Plaza

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K⁺ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.

Original language	English
Pages (from-to)	14859-14861
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	80
DOIs	https://doi.org/10.1039/c5cc06054k
Publication status	Published - 2015 Aug 18

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c5cc06054k

Cite this

@article{c20154b51def4a1ba65c6ecfc0d6e943,

title = "Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores",

abstract = "We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K+ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.",

author = "Nadia Dozova and Rajesh Kumar and Tuhin Pradhan and Fabien Lacombat and Bernard Valeur and Kim, {Jong Seung} and Pascal Plaza",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "18",

doi = "10.1039/c5cc06054k",

language = "English",

volume = "51",

pages = "14859--14861",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "80",

}

TY - JOUR

T1 - Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores

AU - Dozova, Nadia

AU - Kumar, Rajesh

AU - Pradhan, Tuhin

AU - Lacombat, Fabien

AU - Valeur, Bernard

AU - Kim, Jong Seung

AU - Plaza, Pascal

PY - 2015/8/18

Y1 - 2015/8/18

N2 - We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K+ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.

AB - We present a new molecular shuttle, consisting of a calixarene core attached to two different photoactive centers, DCM and DMABN. We show that a K+ ion bound to the DCM-grafted crown is translocated towards the other site of the molecule upon photoexcitation, but not released to the bulk.

UR - http://www.scopus.com/inward/record.url?scp=84942474410&partnerID=8YFLogxK

U2 - 10.1039/c5cc06054k

DO - 10.1039/c5cc06054k

M3 - Article

AN - SCOPUS:84942474410

VL - 51

SP - 14859

EP - 14861

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 80

ER -

Photo-induced cation translocation in a molecular shuttle based on a calix[4]-biscrown including DCM and DMABN chromophores

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this