Photoelectrochemical performance of CdS/ZnSe core/shell nanorods grown on FTO substrates for hydrogen generation

Ki Hyun Cho, Yun Mo Sung

Research output: Contribution to journalArticle

Abstract

One-dimensional nanostructured CdS/ZnSe core/shell photoelectrodes were prepared to show improved photocatalytic properties compared to CdS thin film photoelectrodes. The enhanced surface area and the type-II energy band structure originating from the nanorod growth and ZnSe nanoparticle decoration, respectively, are attributed to the improved photoelectrochemical performance. A mild solution based approach enabled the formation of uniform and high-density CdS nanorods having a diameter and a length of ∼15–20 nm and < 1 μm, respectively. As-synthesized CdS nanorods were uniformly coated with ZnSe nanoparticles to form ZnSe shell with ∼3 nm thickness using a spin coating method. According to the energy bandgaps of CdS nanorods and ZnSe nanoparticles estimated by UV-Visible spectrum analyses, their energy band alignment was expected to be the type-II band structure. This type-II band structure could induce the charge separation of carriers in the semiconductor electrodes and in turn could accelerate the photocatalytic reactions for efficient water splitting not only at lower but also at higher bias voltages compared to CdS thin film electrodes and bare CdS nanorod electrodes.

Original languageEnglish
Pages (from-to)H382-H388
JournalJournal of the Electrochemical Society
Volume164
Issue number6
DOIs
Publication statusPublished - 2017

Fingerprint

Nanorods
Band structure
nanorods
Hydrogen
Substrates
hydrogen
Nanoparticles
nanoparticles
Electrodes
energy bands
electrodes
Thin films
water splitting
Spin coating
polarization (charge separation)
thin films
Bias voltage
visible spectrum
coating
Energy gap

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Electrochemistry

Cite this

Photoelectrochemical performance of CdS/ZnSe core/shell nanorods grown on FTO substrates for hydrogen generation. / Cho, Ki Hyun; Sung, Yun Mo.

In: Journal of the Electrochemical Society, Vol. 164, No. 6, 2017, p. H382-H388.

Research output: Contribution to journalArticle

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