Physical agglomeration behavior in preparation of cellulose-N-methyl morpholine N-oxide hydrate solutions by simple mixing

Dong Bok Kim, Seong Mu Jo, Wha Seop Lee, James Jungho Pak

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The different melting temperatures of N-methyl morpholine N-oxide (NMMO) hydrates in the cellulose-NMMO hydrate solution may be explained by the rather different crystal structures of NMMO hydrates, which are determined by the amount of the hydrates. The preparative process of cellulose-NMMO hydrate solution may result in cellulose structural change from cellulose I to cellulose II, depending on the amount of the hydrate. Mixtures of cellulose and NMMO hydrate in a blender was changed from the granules to slurry with increasing mixing time at 60-70°C, which is below the melting point of the NMMO hydrate. In the case of 15 wt % cellulose-NMMO hydrate granules, which were made by mixing for 20 min, the melting points of various NMMO hydrates were obtained as 77.8°C (n = 0.83), 70.2°C (n = 0.97), and 69.7°C (n = 1.23), respectively, depending on the hydrate number. However, the melting points of cellulose-NMMO hydrate slurry and solution were shifted lower than those of cellulose granules, while the mixing time of slurry and solution are 25 and 35 min, respectively. These melting behaviors indicate instantaneous liquefaction of the NMMO hydrate and the diffusion of the NMMO hydrate into cellulose during mixing in a blender. When cellulose was completely dissolved in NMMO hydrate, the crystal structure of cellulose showed only cellulose II structure. In the cellulose-NMMO products of granules or slurry obtained by high-speed mixing, which is a new preparation method, they still retained, the original cellulose I structure.

Original languageEnglish
Pages (from-to)1687-1697
Number of pages11
JournalJournal of Applied Polymer Science
Volume93
Issue number4
DOIs
Publication statusPublished - 2004 Aug 15

Keywords

  • Agglomeration
  • Cellulose
  • Lyocell
  • N-methyl morpholine n-oxide
  • Solution

ASJC Scopus subject areas

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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