Pinhole-free TiO 2 /Ag (O) /ZnO configuration for flexible perovskite solar cells with ultralow optoelectrical loss

Eunwook Jeong, Soohyun Bae, Jong Bae Park, Seung Min Yu, Donghwan Kim, Haeseok Lee, Jongjoo Rha, Young Rae Cho, Jungheum Yun

Research output: Contribution to journalArticle

Abstract

Perovskite solar cells (PSCs) fabricated on transparent polymer substrates are considered a promising candidate as flexible solar cells that can emulate the advantages of organic solar cells, which exhibit considerable freedom in their device design thanks to their light weight and mechanically flexibility while achieving high photocurrent conversion efficiency, comparable to that of their conventional counterparts fabricated on rigid glasses. However, the full realization of highly efficient, flexible PSCs is largely prevented by technical difficulties in simultaneously attaining a transparent electrode with efficient charge transport to meet the specifications of PSCs. In this study, an effective strategy for resolving this technical issue has been devised by proposing a simple but highly effective technique to fabricate an efficient, multilayer TiO 2 /Ag (O) /ZnO (TAOZ) configuration. This configuration displays low losses in optical transmittance and electrical conductivity owing to its completely continuous, ultrathin metallic Ag (O) transparent electrode, and any notable current leakage is suppressed by its pinhole-free TiO 2 electron transport layer. These features are a direct consequence of the rapid evolution of Ag (O) and TiO 2 into ultrathin, completely continuous, pinhole-free layers owing to the dramatically improved wetting of metallic Ag (O) with a minimal dose of oxygen (ca. 3 at%) during sputtering. The TAOZ configuration exhibits an average transmittance of 88.5% in the spectral range of 400-800 nm and a sheet resistance of 8.4 Ω sq -1 while demonstrating superior mechanical flexibility to that of the conventional TiO 2 on ITO configuration. The photocurrent conversion efficiency of flexible PSCs is significantly improved by up to 11.2% thanks to an optimum combination of optoelectrical performance and pinhole-free morphologies in the TAOZ configuration.

Original languageEnglish
Pages (from-to)9160-9170
Number of pages11
JournalRSC Advances
Volume9
Issue number16
DOIs
Publication statusPublished - 2019 Jan 1

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Photocurrents
Conversion efficiency
Electrodes
Sheet resistance
Opacity
Leakage currents
Sputtering
Wetting
Charge transfer
Solar cells
Polymers
Multilayers
Oxygen
Specifications
Glass
Perovskite solar cells
Substrates
Organic solar cells
Electric Conductivity
Electron Transport

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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Pinhole-free TiO 2 /Ag (O) /ZnO configuration for flexible perovskite solar cells with ultralow optoelectrical loss . / Jeong, Eunwook; Bae, Soohyun; Park, Jong Bae; Yu, Seung Min; Kim, Donghwan; Lee, Haeseok; Rha, Jongjoo; Cho, Young Rae; Yun, Jungheum.

In: RSC Advances, Vol. 9, No. 16, 01.01.2019, p. 9160-9170.

Research output: Contribution to journalArticle

Jeong, Eunwook ; Bae, Soohyun ; Park, Jong Bae ; Yu, Seung Min ; Kim, Donghwan ; Lee, Haeseok ; Rha, Jongjoo ; Cho, Young Rae ; Yun, Jungheum. / Pinhole-free TiO 2 /Ag (O) /ZnO configuration for flexible perovskite solar cells with ultralow optoelectrical loss In: RSC Advances. 2019 ; Vol. 9, No. 16. pp. 9160-9170.
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