Platinum-ruthenium heterogeneous catalytic anodes prepared by atomic layer deposition for use in direct methanol solid oxide fuel cells

Heon Jae Jeong, Jun Woo Kim, Kiho Bae, Hojean Jung, Joon Hyung Shim

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Heterogeneous Pt-Ru catalysts are synthesized by atomic layer deposition (ALD) of Ru onto a porous Pt mesh and employed as the anode in direct methanol solid oxide fuel cells (DMSOFCs). The degree of Ru coverage is controlled by the number of deposition cycles employed in catalyst preparation; samples are prepared using 50, 100, 200, 300, and 400 cycles. The dispersed nature of the ALD Ru coating is confirmed by auger electron spectroscopy and high-resolution transmission electron microscopy. DMSOFC performance is measured at several temperatures between 300 and 450 °C. Optimal ALD Ru coverage results in DMSOFC power and electrode impedance values close to ones from SOFCs with Pt electrodes running on hydrogen. Thermal stability is also improved significantly, preventing agglomeration of the Pt mesh. X-ray photoelectron spectroscopy is used to analyze the chemical properties of the surface and confirms that increased ALD Ru coverage results in a dramatic reduction in the amount of surface-bound carbon monoxide (CO) present after cell operation. This suggests that improved anode kinetics resulted from the reduction of the CO-passivated Pt layer.

Original languageEnglish
Pages (from-to)1914-1921
Number of pages8
JournalACS Catalysis
Volume5
Issue number3
DOIs
Publication statusPublished - 2015 Mar 6

Fingerprint

Ruthenium
Direct methanol fuel cells (DMFC)
Atomic layer deposition
Platinum
Solid oxide fuel cells (SOFC)
Anodes
Carbon Monoxide
Carbon monoxide
Electrodes
Catalysts
Auger electron spectroscopy
High resolution transmission electron microscopy
Chemical properties
Hydrogen
Thermodynamic stability
Agglomeration
X ray photoelectron spectroscopy
Coatings
Kinetics
Temperature

Keywords

  • atomic layer deposition
  • direct methanol solid oxide fuel cell
  • heterogeneous catalysts
  • platinum
  • ruthenium

ASJC Scopus subject areas

  • Catalysis

Cite this

Platinum-ruthenium heterogeneous catalytic anodes prepared by atomic layer deposition for use in direct methanol solid oxide fuel cells. / Jeong, Heon Jae; Kim, Jun Woo; Bae, Kiho; Jung, Hojean; Shim, Joon Hyung.

In: ACS Catalysis, Vol. 5, No. 3, 06.03.2015, p. 1914-1921.

Research output: Contribution to journalArticle

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