Polarization-controlled chiroptical and 2D optical spectroscopy

Kyungwon Kwak, Kwang Hee Park, Minhaeng Cho

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

On a microscopic level, many molecular processes occur on femtosecond (10-15 s) and picosecond (10-12 s) timescales. For example, electron and proton transfers take place in a few femtoseconds and picoseconds, respectively. Water molecules reorient in a few picoseconds in liquids and exchange their hydrogen-bond partners in several picoseconds in aqueous solutions [1,2]. Carbon-carbon bond rotates in tens of picoseconds [3]. Solvent molecules around a solute can reorganize on subpicosecond and picosecond timescales upon an electronic perturbation of the solute [4,5].

Original languageEnglish
Title of host publicationUltrafast Infrared Vibrational Spectroscopy
PublisherCRC Press
Pages203-238
Number of pages36
ISBN (Electronic)9781466510142
ISBN (Print)9781466510135
DOIs
Publication statusPublished - 2013 Jan 1

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Engineering(all)
  • Chemistry(all)

Cite this

Kwak, K., Park, K. H., & Cho, M. (2013). Polarization-controlled chiroptical and 2D optical spectroscopy. In Ultrafast Infrared Vibrational Spectroscopy (pp. 203-238). CRC Press. https://doi.org/10.1201/b13972