Polybenzimidazole (PBI-OO) based composite membranes using sulfophenylated TiO2 as both filler and crosslinker, and their use in the HT-PEM fuel cell

N. Nambi Krishnan, Sangrae Lee, Ravindra V. Ghorpade, Anastasiia Konovalova, Jong Hyun Jang, Hyoung Juhn Kim, Jonghee Han, Dirk Henkensmeier, Haksoo Han

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Crosslinked metal oxide containing nanocomposite membranes, in which the filler also acts as crosslinker, were prepared by blending polybenzimidazole (PBI-OO) and phenylsulfonated TiO2 particles (s-TiO2). Thermal curing changes the ionically crosslinked system into a covalently crosslinked system. The synthesized s-TiO2 nanoparticles were analyzed by thermal gravimetric analysis and scanning electron microscopy. The covalently crosslinked nanocomposite membranes (c-sTiO2-PBI-OO) were doped with phosphoric acid (PA) for high temperature proton exchange membrane fuel cell (HT-PEMFC) application. The membrane properties, such as PA uptake, dimensional change, gel content, proton conductivity, mechanical property, and single cell performance were evaluated and compared with the properties of acid-doped c-PBI-OO. PA doped 6-c-sTiO2-PBI-OO (6 wt% sTiO2) showed the highest uptake of 392 wt%, and a proton conductivity at 160 °C of 98 mS cm−1. In the fuel cell, a peak power density of 356 mW cm−2 was obtained, which is 76% higher than that of a c-PBI-OO based system (202 mW cm−2). To evaluate the stability of the membrane performance over time, the best performing membrane was tested for over 700 h.

Original languageEnglish
Pages (from-to)11-20
Number of pages10
JournalJournal of Membrane Science
Volume560
DOIs
Publication statusPublished - 2018 Aug 15
Externally publishedYes

Fingerprint

polybenzimidazole
Composite membranes
fillers
fuel cells
Fillers
Fuel cells
membranes
Membranes
Phosphoric acid
composite materials
phosphoric acid
Protons
Nanocomposites
Proton conductivity
Hot Temperature
protons
nanocomposites
Gravimetric analysis
Proton exchange membrane fuel cells (PEMFC)
conductivity

Keywords

  • HT-PEMFC
  • Nanocomposite membrane
  • PBI-OO
  • Sulfophenylated TiO
  • Thermal crosslinking

ASJC Scopus subject areas

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

Polybenzimidazole (PBI-OO) based composite membranes using sulfophenylated TiO2 as both filler and crosslinker, and their use in the HT-PEM fuel cell. / Krishnan, N. Nambi; Lee, Sangrae; Ghorpade, Ravindra V.; Konovalova, Anastasiia; Jang, Jong Hyun; Kim, Hyoung Juhn; Han, Jonghee; Henkensmeier, Dirk; Han, Haksoo.

In: Journal of Membrane Science, Vol. 560, 15.08.2018, p. 11-20.

Research output: Contribution to journalArticle

Krishnan, N. Nambi ; Lee, Sangrae ; Ghorpade, Ravindra V. ; Konovalova, Anastasiia ; Jang, Jong Hyun ; Kim, Hyoung Juhn ; Han, Jonghee ; Henkensmeier, Dirk ; Han, Haksoo. / Polybenzimidazole (PBI-OO) based composite membranes using sulfophenylated TiO2 as both filler and crosslinker, and their use in the HT-PEM fuel cell. In: Journal of Membrane Science. 2018 ; Vol. 560. pp. 11-20.
@article{2aa27eb5ab4244bf988ab5f17cf74cb9,
title = "Polybenzimidazole (PBI-OO) based composite membranes using sulfophenylated TiO2 as both filler and crosslinker, and their use in the HT-PEM fuel cell",
abstract = "Crosslinked metal oxide containing nanocomposite membranes, in which the filler also acts as crosslinker, were prepared by blending polybenzimidazole (PBI-OO) and phenylsulfonated TiO2 particles (s-TiO2). Thermal curing changes the ionically crosslinked system into a covalently crosslinked system. The synthesized s-TiO2 nanoparticles were analyzed by thermal gravimetric analysis and scanning electron microscopy. The covalently crosslinked nanocomposite membranes (c-sTiO2-PBI-OO) were doped with phosphoric acid (PA) for high temperature proton exchange membrane fuel cell (HT-PEMFC) application. The membrane properties, such as PA uptake, dimensional change, gel content, proton conductivity, mechanical property, and single cell performance were evaluated and compared with the properties of acid-doped c-PBI-OO. PA doped 6-c-sTiO2-PBI-OO (6 wt{\%} sTiO2) showed the highest uptake of 392 wt{\%}, and a proton conductivity at 160 °C of 98 mS cm−1. In the fuel cell, a peak power density of 356 mW cm−2 was obtained, which is 76{\%} higher than that of a c-PBI-OO based system (202 mW cm−2). To evaluate the stability of the membrane performance over time, the best performing membrane was tested for over 700 h.",
keywords = "HT-PEMFC, Nanocomposite membrane, PBI-OO, Sulfophenylated TiO, Thermal crosslinking",
author = "Krishnan, {N. Nambi} and Sangrae Lee and Ghorpade, {Ravindra V.} and Anastasiia Konovalova and Jang, {Jong Hyun} and Kim, {Hyoung Juhn} and Jonghee Han and Dirk Henkensmeier and Haksoo Han",
year = "2018",
month = "8",
day = "15",
doi = "10.1016/j.memsci.2018.05.006",
language = "English",
volume = "560",
pages = "11--20",
journal = "Jornal of Membrane Science",
issn = "0376-7388",
publisher = "Elsevier",

}

TY - JOUR

T1 - Polybenzimidazole (PBI-OO) based composite membranes using sulfophenylated TiO2 as both filler and crosslinker, and their use in the HT-PEM fuel cell

AU - Krishnan, N. Nambi

AU - Lee, Sangrae

AU - Ghorpade, Ravindra V.

AU - Konovalova, Anastasiia

AU - Jang, Jong Hyun

AU - Kim, Hyoung Juhn

AU - Han, Jonghee

AU - Henkensmeier, Dirk

AU - Han, Haksoo

PY - 2018/8/15

Y1 - 2018/8/15

N2 - Crosslinked metal oxide containing nanocomposite membranes, in which the filler also acts as crosslinker, were prepared by blending polybenzimidazole (PBI-OO) and phenylsulfonated TiO2 particles (s-TiO2). Thermal curing changes the ionically crosslinked system into a covalently crosslinked system. The synthesized s-TiO2 nanoparticles were analyzed by thermal gravimetric analysis and scanning electron microscopy. The covalently crosslinked nanocomposite membranes (c-sTiO2-PBI-OO) were doped with phosphoric acid (PA) for high temperature proton exchange membrane fuel cell (HT-PEMFC) application. The membrane properties, such as PA uptake, dimensional change, gel content, proton conductivity, mechanical property, and single cell performance were evaluated and compared with the properties of acid-doped c-PBI-OO. PA doped 6-c-sTiO2-PBI-OO (6 wt% sTiO2) showed the highest uptake of 392 wt%, and a proton conductivity at 160 °C of 98 mS cm−1. In the fuel cell, a peak power density of 356 mW cm−2 was obtained, which is 76% higher than that of a c-PBI-OO based system (202 mW cm−2). To evaluate the stability of the membrane performance over time, the best performing membrane was tested for over 700 h.

AB - Crosslinked metal oxide containing nanocomposite membranes, in which the filler also acts as crosslinker, were prepared by blending polybenzimidazole (PBI-OO) and phenylsulfonated TiO2 particles (s-TiO2). Thermal curing changes the ionically crosslinked system into a covalently crosslinked system. The synthesized s-TiO2 nanoparticles were analyzed by thermal gravimetric analysis and scanning electron microscopy. The covalently crosslinked nanocomposite membranes (c-sTiO2-PBI-OO) were doped with phosphoric acid (PA) for high temperature proton exchange membrane fuel cell (HT-PEMFC) application. The membrane properties, such as PA uptake, dimensional change, gel content, proton conductivity, mechanical property, and single cell performance were evaluated and compared with the properties of acid-doped c-PBI-OO. PA doped 6-c-sTiO2-PBI-OO (6 wt% sTiO2) showed the highest uptake of 392 wt%, and a proton conductivity at 160 °C of 98 mS cm−1. In the fuel cell, a peak power density of 356 mW cm−2 was obtained, which is 76% higher than that of a c-PBI-OO based system (202 mW cm−2). To evaluate the stability of the membrane performance over time, the best performing membrane was tested for over 700 h.

KW - HT-PEMFC

KW - Nanocomposite membrane

KW - PBI-OO

KW - Sulfophenylated TiO

KW - Thermal crosslinking

UR - http://www.scopus.com/inward/record.url?scp=85046869112&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85046869112&partnerID=8YFLogxK

U2 - 10.1016/j.memsci.2018.05.006

DO - 10.1016/j.memsci.2018.05.006

M3 - Article

AN - SCOPUS:85046869112

VL - 560

SP - 11

EP - 20

JO - Jornal of Membrane Science

JF - Jornal of Membrane Science

SN - 0376-7388

ER -