Polyethylene glycol-functionalized siloxane hybrid gel polymer electrolytes for lithium ion batteries

Albert S. Lee, Jin Hong Lee, Jong Chan Lee, Soon Man Hong, Seung Sang Hwang, Chong Min Koo

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The compatibility of diacrylate terminated polyethylene glycol-block-polydimethylsiloxane-blockpolyethylene glycol was examined with an ionic liquid solution, 1 M LiTFSI in N-butyl-Nmethylpyrrolidinium bis(trifluoromethylsulfonyl)imide, and through mild UV-curing, hybrid gel polymer electrolytes were fabricated for lithium ion battery application. Obtained hybrid gel polymer electrolytes exhibited good ionic conductivity, electrochemical stability, thermal stability, and mechanical pliancy and the polyethylene glycol domains functioned to increase the ionic dissociation to improve ion conduction compared with gel polymer electrolytes fabricated with a conventional organic crosslinker. Lithium ion battery cell tests with these hybrid gel polymer electrolytes revealed that these hybrid gel polymer electrolytes hold promise as next generation electrolytes.

Original languageEnglish
Pages (from-to)3016-3020
Number of pages5
JournalJournal of Nanoscience and Nanotechnology
Volume17
Issue number5
DOIs
Publication statusPublished - 2017 Jan 1
Externally publishedYes

Fingerprint

Siloxanes
siloxanes
Lithium
Electrolytes
Polyethylene glycols
electric batteries
glycols
polyethylenes
Polymers
Gels
lithium
electrolytes
gels
Ions
polymers
ions
Imides
Ionic Liquids
Glycols
imides

Keywords

  • Ionic Liquids
  • Lithium Ion Batteries
  • Polymer Electrolytes
  • Polysiloxane

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Biomedical Engineering
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Polyethylene glycol-functionalized siloxane hybrid gel polymer electrolytes for lithium ion batteries. / Lee, Albert S.; Lee, Jin Hong; Lee, Jong Chan; Hong, Soon Man; Hwang, Seung Sang; Koo, Chong Min.

In: Journal of Nanoscience and Nanotechnology, Vol. 17, No. 5, 01.01.2017, p. 3016-3020.

Research output: Contribution to journalArticle

Lee, Albert S. ; Lee, Jin Hong ; Lee, Jong Chan ; Hong, Soon Man ; Hwang, Seung Sang ; Koo, Chong Min. / Polyethylene glycol-functionalized siloxane hybrid gel polymer electrolytes for lithium ion batteries. In: Journal of Nanoscience and Nanotechnology. 2017 ; Vol. 17, No. 5. pp. 3016-3020.
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