Porous Zn2GeO4 nanowires with uniform carbon-buffer layer for lithium-ion battery anodes with long cycle life

Jung Sub Kim, A. Young Kim, Young Woon Byeon, Jae Pyoung Ahn, Dong Jin Byun, Joong Kee Lee

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Germanium-based multimetallic-oxide materials have attracted significant attention as high-capacity anodes for next generation lithium-ion batteries (LIBs). However, they suffer from poor cyclic stability due to extreme volume expansion and reduced electrical conductivity after repeated cycles. To circumvent these issues, we propose that Ge-based multimetallic-oxide nanowires can be synthesized with electrically conductive carbon to significantly enhance the cyclic stability of the Ge-based anodes. We prepare conformal-carbon-coated Zn2GeO4 nanowires (NWs) using a microwave-induced hydrothermal method with subsequent thermal decomposition. The obtained carbon-coated Zn2GeO4-NW anode exhibits a discharge capacity of 485 mAh/g and a Coulombic efficiency (CE) of 98.4% after 900 cycles at 0.6 C. Furthermore, these anodes exhibit outstanding rate-capability characteristics, even with an increased C-rate of 17.7 C. This excellent electrochemical performance can be ascribed to the improved electron and ion transport provided and the structurally reinforced conductive layer comprising a conformal carbon layer. Therefore, it is expected that our approach can also be applied to other multimetallic-oxide materials, resulting in large, reversible capacities; excellent cyclic stabilities; and good rate capabilities for high-performance LIBs.

Original languageEnglish
Pages (from-to)43-50
Number of pages8
JournalElectrochimica Acta
Volume195
DOIs
Publication statusPublished - 2016 Mar 20

Fingerprint

Buffer layers
Nanowires
Life cycle
Anodes
Carbon
Oxides
Germanium
Pyrolysis
Microwaves
Ions
Lithium-ion batteries
zinc germanate
Electrons

Keywords

  • carbon-buffer layers
  • lithium-ion batteries
  • long cycle life
  • nanowires
  • ZnGeO

ASJC Scopus subject areas

  • Electrochemistry
  • Chemical Engineering(all)

Cite this

Porous Zn2GeO4 nanowires with uniform carbon-buffer layer for lithium-ion battery anodes with long cycle life. / Kim, Jung Sub; Kim, A. Young; Byeon, Young Woon; Ahn, Jae Pyoung; Byun, Dong Jin; Lee, Joong Kee.

In: Electrochimica Acta, Vol. 195, 20.03.2016, p. 43-50.

Research output: Contribution to journalArticle

Kim, Jung Sub ; Kim, A. Young ; Byeon, Young Woon ; Ahn, Jae Pyoung ; Byun, Dong Jin ; Lee, Joong Kee. / Porous Zn2GeO4 nanowires with uniform carbon-buffer layer for lithium-ion battery anodes with long cycle life. In: Electrochimica Acta. 2016 ; Vol. 195. pp. 43-50.
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