Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers

Sundol Kim; Kyung Yeon Lee; Young Sun Lee; Ho Gyeom Jang; Jung Kyoo Lee; Suk Joong Lee

doi:10.1142/S1088424614500321

Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers

Sundol Kim, Kyung Yeon Lee, Young Sun Lee, Ho Gyeom Jang, Jung Kyoo Lee, Suk Joong Lee

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.

Original language	English
Pages (from-to)	579-584
Number of pages	6
Journal	Journal of Porphyrins and Phthalocyanines
Volume	18
Issue number	7
DOIs	https://doi.org/10.1142/S1088424614500321
Publication status	Published - 2014

Keywords

coordination polymer
epoxidation
heterogeneous catalysis
isostructural
metal-organic frameworks

ASJC Scopus subject areas

Chemistry(all)

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10.1142/S1088424614500321

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title = "Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers",

abstract = "We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.",

keywords = "coordination polymer, epoxidation, heterogeneous catalysis, isostructural, metal-organic frameworks",

author = "Sundol Kim and Lee, {Kyung Yeon} and Lee, {Young Sun} and Jang, {Ho Gyeom} and Lee, {Jung Kyoo} and Lee, {Suk Joong}",

note = "Funding Information: The authors acknowledge the financial support from the National Research Foundation Program of Korea (NRF 2013R1A1A2007429) and Priority Research Centers Program (NRF20100020209) through the KNRF funded by the Ministry of Education, Science and Technology (MEST).",

year = "2014",

doi = "10.1142/S1088424614500321",

language = "English",

volume = "18",

pages = "579--584",

journal = "Journal of Porphyrins and Phthalocyanines",

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publisher = "Society of Porphyrins and Phthalocyanines (SPP)",

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TY - JOUR

T1 - Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers

AU - Kim, Sundol

AU - Lee, Kyung Yeon

AU - Lee, Young Sun

AU - Jang, Ho Gyeom

AU - Lee, Jung Kyoo

AU - Lee, Suk Joong

N1 - Funding Information: The authors acknowledge the financial support from the National Research Foundation Program of Korea (NRF 2013R1A1A2007429) and Priority Research Centers Program (NRF20100020209) through the KNRF funded by the Ministry of Education, Science and Technology (MEST).

PY - 2014

Y1 - 2014

N2 - We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.

AB - We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.

KW - coordination polymer

KW - epoxidation

KW - heterogeneous catalysis

KW - isostructural

KW - metal-organic frameworks

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DO - 10.1142/S1088424614500321

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SP - 579

EP - 584

JO - Journal of Porphyrins and Phthalocyanines

JF - Journal of Porphyrins and Phthalocyanines

SN - 1088-4246

IS - 7

ER -

Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers

Abstract

Keywords

ASJC Scopus subject areas

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