Abstract
We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.
| Original language | English |
|---|---|
| Pages (from-to) | 579-584 |
| Number of pages | 6 |
| Journal | Journal of Porphyrins and Phthalocyanines |
| Volume | 18 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2014 Jan 1 |
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ASJC Scopus subject areas
- Chemistry(all)
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Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers. / Kim, Sundol; Lee, Kyung Yeon; Lee, Young Sun; Jang, Ho Gyeom; Lee, Jung Kyoo; Lee, Suk Joong.
In: Journal of Porphyrins and Phthalocyanines, Vol. 18, No. 7, 01.01.2014, p. 579-584.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers
AU - Kim, Sundol
AU - Lee, Kyung Yeon
AU - Lee, Young Sun
AU - Jang, Ho Gyeom
AU - Lee, Jung Kyoo
AU - Lee, Suk Joong
PY - 2014/1/1
Y1 - 2014/1/1
N2 - We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.
AB - We developed a series of micro-sized porous coordination polymers from Mn(III)-porphyrin biscarboxylate and In(III) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.
KW - coordination polymer
KW - epoxidation
KW - heterogeneous catalysis
KW - isostructural
KW - metal-organic frameworks
UR - http://www.scopus.com/inward/record.url?scp=84906683904&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84906683904&partnerID=8YFLogxK
U2 - 10.1142/S1088424614500321
DO - 10.1142/S1088424614500321
M3 - Article
VL - 18
SP - 579
EP - 584
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
SN - 1088-4246
IS - 7
ER -