Preparation and characterization of iodinated poly(vinyl alcohol) microfibril

Won Seok Lyoo, Sam Soo Kim, Han Do Ghim, Jae Pil Kim, Ick Chan Kwon, Chul Joo Lee

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Iodination of poly(vinyl alcohol) (PVA) microfibril, which was obtained from saponification of poly(vinyl pivalate), was conducted before and after zone drawing at various conditions. The resulting PVA microfibrils were characterized by differential scanning calorimeter and scanning electron microscopy. Surface morphologies of these PVA microfibrils showed some differences between PVA microfibril iodinated after and before drawing. Crude shapes of PVA microfibrils iodinated after drawing indicated that iodine decreased the structural regularity severely. On the other hand, PVA microfibrils iodinated before drawing showed relatively ordered surfaces. This was ascribed to the enhanced molecular ordering of PVA microfibrils due on zone drawing. Iodinated PVA micro fibrils showed a decrease in crystal melting temperature of about 100°C compared to the untreated sample. PVA microfibrils drawn after iodination showed relatively higher crystal melting temperature than those of microfibrils iodinated after drawing. These results were considered as the proofs of the changes in crystalline lattice of the PVA micro fibrils. Effects of drawing temperature on sublimation of iodine were also evaluated.

Original languageEnglish
Pages (from-to)125-131
Number of pages7
JournalMacromolecular Symposia
Volume180
DOIs
Publication statusPublished - 2002 Apr 29
Externally publishedYes

Fingerprint

Iodine
Melting point
alcohols
Alcohols
Saponification
preparation
Crystals
Sublimation
Calorimeters
Crystal lattices
Surface morphology
Crystalline materials
Scanning
Scanning electron microscopy
iodine
melting
Temperature
sublimation
regularity
crystals

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Preparation and characterization of iodinated poly(vinyl alcohol) microfibril. / Lyoo, Won Seok; Kim, Sam Soo; Ghim, Han Do; Kim, Jae Pil; Kwon, Ick Chan; Lee, Chul Joo.

In: Macromolecular Symposia, Vol. 180, 29.04.2002, p. 125-131.

Research output: Contribution to journalArticle

Lyoo, Won Seok ; Kim, Sam Soo ; Ghim, Han Do ; Kim, Jae Pil ; Kwon, Ick Chan ; Lee, Chul Joo. / Preparation and characterization of iodinated poly(vinyl alcohol) microfibril. In: Macromolecular Symposia. 2002 ; Vol. 180. pp. 125-131.
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