Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

Jigyoung Yi, Hye Mi Ahn, Jong Ho Yoon, Cheal Kim, Suk Joong Lee

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent immobilization of CuCl2 gave POP-Cu(ii). This new heterogeneous catalyst displayed outstanding olefin oxidation activity compared to its homogeneous analogue, suggesting that the degradation of the homogeneous catalyst was successfully inhibited by site isolation.

Original languageEnglish
Pages (from-to)14067-14070
Number of pages4
JournalNew Journal of Chemistry
Volume42
Issue number17
DOIs
Publication statusPublished - 2018 Jan 1

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

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