@inbook{b308c7ad7c294286afa8cd22730b5715,
title = "Preparation of heteropolyacid/carbon catalyst and its application to methacrolein oxidation",
abstract = "CMK-3 was prepared using SBA-15 as a removable templating material, and the surface of CMK-3 was chemically modified to have the positive charge. H3PMo12O40 (PMo12) was then immobilized on the surface modified CMK-3 (SM-CMK-3) as a charge compensating component, by taking advantage of the overall negative charge of [PMo12O40]3-. The supported H3PMo12O40/SM- was characterized to have high surface area (ca. 1000 m2/g) and relatively large pore volume (0.83 cm3/g). In the catalytic oxidation of methacrolein, conversion of methacrolein and yield for methacrylic acid were increased in the order of bulk H3PMo12O40<H3PMo12O40/CMK-3<H3PMo12O40/SM The enhanced catalytic performance of H3PMo12O40/SM-CMK-3 was due to the fine dispersion of H3PMo12O40 species supported on SM-CMK-3 via chemical immobilization. The catalyst preparation method suggested in this work was very efficient for the model surface-type catalytic oxidation of methacrolein.",
author = "Heesoo Kim and Jung, {Ji Chul} and Pil Kim and Lee, {Kwan Young} and Yeom, {Sung Ho} and Song, {In Kyu}",
note = "Funding Information: The authors acknowledge the support from Korea Science and Engineering Foundation (KOSEF R01-2004-000-10502-0). Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",
year = "2006",
doi = "10.1016/S0167-2991(06)80983-3",
language = "English",
isbn = "044452827X",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier Inc.",
pages = "801--808",
booktitle = "Scientific Bases for the Preparation of Heterogeneous Catalysts",
}