Preparation of La1-xSrxMnO3 powders by combustion of poly(ethylene glycol)-metal nitrate gel precursors

Hyu Bum Park, Ho Jin Kweon, Young Sik Hong, Si Joong Kim, Keon Kim

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43 Citations (Scopus)

Abstract

La1-xSrxMnO3 powders were prepared by auto-ignited combustion of poly(ethylene glycol) (PEG) metal nitrate gel precursors. The thermal behaviour of the precursors strongly depends on the ratio of PEG to metal nitrate, which is closely related to the ratio of fuel to oxidizer. The burning behaviour in a furnace was successfully explained by valence concepts normally encountered in propellant chemistry. The formation of a pure perovskite phase was significantly influenced by the homogeneity of the gel precursor. Perovskite structured oxides were formed through two different paths, one of which was direct formation from the burning of a gel precursor and the other was a subsequent structural evolution by heat treatment after burning. The formation procedure of the perovskite and the morphology of powders could be explained in terms of the burning behaviour of the precursor and the role of organic residue.

Original languageEnglish
Pages (from-to)57-65
Number of pages9
JournalJournal of Materials Science
Volume32
Issue number1
Publication statusPublished - 1997 Dec 1

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Nitrates
Powders
Polyethylene glycols
Gels
Metals
Perovskite
Propellants
Oxides
Furnaces
Heat treatment
perovskite

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Preparation of La1-xSrxMnO3 powders by combustion of poly(ethylene glycol)-metal nitrate gel precursors. / Park, Hyu Bum; Kweon, Ho Jin; Hong, Young Sik; Kim, Si Joong; Kim, Keon.

In: Journal of Materials Science, Vol. 32, No. 1, 01.12.1997, p. 57-65.

Research output: Contribution to journalArticle

Park, Hyu Bum ; Kweon, Ho Jin ; Hong, Young Sik ; Kim, Si Joong ; Kim, Keon. / Preparation of La1-xSrxMnO3 powders by combustion of poly(ethylene glycol)-metal nitrate gel precursors. In: Journal of Materials Science. 1997 ; Vol. 32, No. 1. pp. 57-65.
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