Promoters for the (Alkyne) hexacarbonyldicobalt-Based Cyclopentenone Synthesis

Young Keun Chung, Bun Yeoul Lee, Nakcheol Jeong, Milan Hudecek, Peter L. Pauson

Research output: Contribution to journalArticle

159 Citations (Scopus)

Abstract

Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.

Original languageEnglish
Pages (from-to)220-223
Number of pages4
JournalOrganometallics
Volume12
Issue number1
DOIs
Publication statusPublished - 1993
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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  • Cite this

    Chung, Y. K., Lee, B. Y., Jeong, N., Hudecek, M., & Pauson, P. L. (1993). Promoters for the (Alkyne) hexacarbonyldicobalt-Based Cyclopentenone Synthesis. Organometallics, 12(1), 220-223. https://doi.org/10.1021/om00025a036