Promoters for the (alkyne)hexacarbonyldicobalt-based cyclopentenone synthesis

Young Keun Chung, Bun Yeoul Lee, Nakcheol Jeong, Milan Hudecek, Peter L. Pauson

Research output: Contribution to journalArticle

159 Citations (Scopus)

Abstract

Dimethyl sulfoxide and a variety of other highly polar solvents are shown to promote both inter- and intramolecular cyclopentenone formation from alkenes and (alkyne)hexacarbonyldicobalt complexes. Their use leads to significant changes in both regio- and stereoselectivity when compared to other reaction conditions.

Original languageEnglish
Pages (from-to)220-223
Number of pages4
JournalOrganometallics
Volume12
Issue number1
Publication statusPublished - 1993 Dec 1
Externally publishedYes

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Stereoselectivity
Regioselectivity
Alkynes
Alkenes
alkynes
Dimethyl Sulfoxide
alkenes
synthesis
cyclopentenone

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Chung, Y. K., Lee, B. Y., Jeong, N., Hudecek, M., & Pauson, P. L. (1993). Promoters for the (alkyne)hexacarbonyldicobalt-based cyclopentenone synthesis. Organometallics, 12(1), 220-223.

Promoters for the (alkyne)hexacarbonyldicobalt-based cyclopentenone synthesis. / Chung, Young Keun; Lee, Bun Yeoul; Jeong, Nakcheol; Hudecek, Milan; Pauson, Peter L.

In: Organometallics, Vol. 12, No. 1, 01.12.1993, p. 220-223.

Research output: Contribution to journalArticle

Chung, YK, Lee, BY, Jeong, N, Hudecek, M & Pauson, PL 1993, 'Promoters for the (alkyne)hexacarbonyldicobalt-based cyclopentenone synthesis', Organometallics, vol. 12, no. 1, pp. 220-223.
Chung YK, Lee BY, Jeong N, Hudecek M, Pauson PL. Promoters for the (alkyne)hexacarbonyldicobalt-based cyclopentenone synthesis. Organometallics. 1993 Dec 1;12(1):220-223.
Chung, Young Keun ; Lee, Bun Yeoul ; Jeong, Nakcheol ; Hudecek, Milan ; Pauson, Peter L. / Promoters for the (alkyne)hexacarbonyldicobalt-based cyclopentenone synthesis. In: Organometallics. 1993 ; Vol. 12, No. 1. pp. 220-223.
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