Pure and palladium-loaded Co3O4 hollow hierarchical nanostructures with giant and ultraselective chemiresistivity to xylene and toluene

Su Jin Hwang, Kwon Il Choi, Ji Wook Yoon, Yun Chan Kang, Jong Heun Lee

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Pure and palladium-loaded Co3O4 hollow hierarchical nanostructures consisting of nanosheets have been prepared by solvothermal self-assembly. The nanostructures exhibited an ultrahigh response and selectivity towards p-xylene and toluene. The responses (resistance ratio) of the palladium-loaded Co3O4 hollow hierarchical nanostructures to 5 ppm of p-xylene and toluene were as high as 361 and 305, respectively, whereas the selectivity values (response ratios) towards p-xylene and toluene over interference from ethanol were 18.1 and 16.1, respectively. We attributed the giant response and unprecedented high selectivity towards methylbenzenes to the abundant adsorption of oxygen by Co3O4, the high chemiresistive variation in the Co3O4 nanosheets (thickness≈11 nm), and the catalytic promotion of the specific gas-sensing reaction. The morphological design of the p-type Co3O4 nanostructures and loading of the palladium catalyst have paved a new way to monitoring the most representative indoor air pollutants in a highly selective, sensitive, and reliable manner.

Original languageEnglish
Pages (from-to)5872-5878
Number of pages7
JournalChemistry (Weinheim an der Bergstrasse, Germany)
Volume21
Issue number15
DOIs
Publication statusPublished - 2015 Apr 7

Fingerprint

Xylenes
Nanostructures
Toluene
Palladium
Nanosheets
Air Pollutants
Self assembly
Adsorption
Ethanol
Gases
Oxygen
Catalysts
Monitoring
4-xylene

Keywords

  • cobalt
  • methylbenzenes
  • nanostructures
  • palladium
  • sensors

ASJC Scopus subject areas

  • Medicine(all)

Cite this

Pure and palladium-loaded Co3O4 hollow hierarchical nanostructures with giant and ultraselective chemiresistivity to xylene and toluene. / Hwang, Su Jin; Choi, Kwon Il; Yoon, Ji Wook; Kang, Yun Chan; Lee, Jong Heun.

In: Chemistry (Weinheim an der Bergstrasse, Germany), Vol. 21, No. 15, 07.04.2015, p. 5872-5878.

Research output: Contribution to journalArticle

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