Pyrene-armed calix[4]azacrowns as new fluorescent ionophores

"Molecular taekowndo" process via fluorescence change

Jong Seung Kim, Ok Jae Shon, Jeong Ah Rim, Sook Kyung Kim, Juyoung Yoon

Research output: Contribution to journalArticle

151 Citations (Scopus)

Abstract

A series of new calixarene-based fluoroionophores were synthesized. With our new calixarene derivative bearing a crown ether and an azacrown ether as two binding sites, the metal ion was found to selectively choose its better binding pocket between these two ligands. Interesting "molecular taekowndo" processes between Ag+-K+, Cu2+-K+, and Ag+-Cs+ pairs were easily monitored via fluorescence change.

Original languageEnglish
Pages (from-to)2348-2351
Number of pages4
JournalJournal of Organic Chemistry
Volume67
Issue number7
DOIs
Publication statusPublished - 2002 Apr 5
Externally publishedYes

Fingerprint

Calixarenes
Ionophores
Bearings (structural)
Fluorescence
Crown Ethers
Ether
Metal ions
Metals
Binding Sites
Ions
Ligands
Derivatives
pyrene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Pyrene-armed calix[4]azacrowns as new fluorescent ionophores : "Molecular taekowndo" process via fluorescence change. / Kim, Jong Seung; Shon, Ok Jae; Rim, Jeong Ah; Kim, Sook Kyung; Yoon, Juyoung.

In: Journal of Organic Chemistry, Vol. 67, No. 7, 05.04.2002, p. 2348-2351.

Research output: Contribution to journalArticle

Kim, Jong Seung ; Shon, Ok Jae ; Rim, Jeong Ah ; Kim, Sook Kyung ; Yoon, Juyoung. / Pyrene-armed calix[4]azacrowns as new fluorescent ionophores : "Molecular taekowndo" process via fluorescence change. In: Journal of Organic Chemistry. 2002 ; Vol. 67, No. 7. pp. 2348-2351.
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