Pyrolysis kinetics of waste automobile lubricating oil

S. S. Kim, S. H. Kim

Research output: Contribution to journalArticlepeer-review

49 Citations (Scopus)

Abstract

The kinetics of waste automobile lubricating oil have been studied experimentally and modeled mathematically. Experiments were carried out in the tubing bomb microreactor at a temperature of 420-440 °C and reaction times of 5-50 min. Volatile pyrolysis products were identified and quantitatively determined by gas chromotography. A lump model of combined series and parallel reactions for oil formation is proposed. Conversion data fitted first order kinetics for C5-C11 and C12-C25. The kinetic parameters were determined by nonlinear least-squares regression of the experimental data. These calculated values of the product distribution were found to be in agreement with the experimental data.

Original languageEnglish
Pages (from-to)1943-1949
Number of pages7
JournalFuel
Volume79
Issue number15
DOIs
Publication statusPublished - 2000 Dec

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Organic Chemistry

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