Quantitative elucidation of the elusive role of defects in polycrystalline MFI zeolite membranes on xylene separation performance

Sungwon Hong, Dongjae Kim, Hannes Richter, Jong Ho Moon, Nakwon Choi, Jaewook Nam, Jungkyu Choi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The defect structure in a c-out-of-plane oriented MFI membrane was quantitatively analyzed by processing images obtained by fluorescence confocal optical microscopy (FCOM). The MFI membranes were placed in contact with a dye solution at a fixed concentration (1 mM) for 2, 4, and 8 d and at different concentrations (0.01, 0.1, and 1 mM) for 8 d. This approach led to the identification and understanding of two types of defects (cracks and grain boundary defects). The representative quantitative properties (porosity and tortuosity) relevant to the defects were obtained via the image processing. Furthermore, the estimation of the defect sizes was complemented by the use of a one-dimensional permeation model for the molar flux of the p-/o-xylene components across the c-oriented MFI membrane. Using this combination, we found that although the amount of defects in the whole zeolite membrane was close to ~ 1%, they provided non-selective, facile pathways that accounted for ~ 58% of the total molar flux of faster permeating p-xylene. Surprisingly, despite the lower density (pixel-based area fraction) of cracks, wider cracks (~ 7.8–8.2 nm) accounted for the much higher molar flux of permeation components compared to major, but narrower grain boundary defects (~ 1–2 nm). Indeed, the cracks mainly deteriorated a p-/o-xylene separation performance of the c-oriented MFI membrane. Finally, we found that the crack size increased in the presence of p-xylene so that the molar flux of o-xylene in the binary mixture was significantly increased, thus reducing the p-/o-xylene separation performance. This behavior was ascribed to the flexible MFI zeolite structure after the adsorption of p-xylene.

Original languageEnglish
Pages (from-to)91-103
Number of pages13
JournalJournal of Membrane Science
Volume569
DOIs
Publication statusPublished - 2019 Jan 1

Fingerprint

Zeolites
Xylenes
xylene
Xylene
membranes
Membranes
Defects
Cracks
cracks
defects
Fluxes
Permeation
Grain boundaries
Image processing
image processing
grain boundaries
permeating
Confocal microscopy
Defect structures
Porosity

Keywords

  • Cracks
  • Fluorescence confocal optical microscopy (FCOM)
  • Grain boundary defects
  • Quantitative image processing
  • Zeolite membranes

ASJC Scopus subject areas

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

Quantitative elucidation of the elusive role of defects in polycrystalline MFI zeolite membranes on xylene separation performance. / Hong, Sungwon; Kim, Dongjae; Richter, Hannes; Moon, Jong Ho; Choi, Nakwon; Nam, Jaewook; Choi, Jungkyu.

In: Journal of Membrane Science, Vol. 569, 01.01.2019, p. 91-103.

Research output: Contribution to journalArticle

Hong, Sungwon ; Kim, Dongjae ; Richter, Hannes ; Moon, Jong Ho ; Choi, Nakwon ; Nam, Jaewook ; Choi, Jungkyu. / Quantitative elucidation of the elusive role of defects in polycrystalline MFI zeolite membranes on xylene separation performance. In: Journal of Membrane Science. 2019 ; Vol. 569. pp. 91-103.
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abstract = "The defect structure in a c-out-of-plane oriented MFI membrane was quantitatively analyzed by processing images obtained by fluorescence confocal optical microscopy (FCOM). The MFI membranes were placed in contact with a dye solution at a fixed concentration (1 mM) for 2, 4, and 8 d and at different concentrations (0.01, 0.1, and 1 mM) for 8 d. This approach led to the identification and understanding of two types of defects (cracks and grain boundary defects). The representative quantitative properties (porosity and tortuosity) relevant to the defects were obtained via the image processing. Furthermore, the estimation of the defect sizes was complemented by the use of a one-dimensional permeation model for the molar flux of the p-/o-xylene components across the c-oriented MFI membrane. Using this combination, we found that although the amount of defects in the whole zeolite membrane was close to ~ 1{\%}, they provided non-selective, facile pathways that accounted for ~ 58{\%} of the total molar flux of faster permeating p-xylene. Surprisingly, despite the lower density (pixel-based area fraction) of cracks, wider cracks (~ 7.8–8.2 nm) accounted for the much higher molar flux of permeation components compared to major, but narrower grain boundary defects (~ 1–2 nm). Indeed, the cracks mainly deteriorated a p-/o-xylene separation performance of the c-oriented MFI membrane. Finally, we found that the crack size increased in the presence of p-xylene so that the molar flux of o-xylene in the binary mixture was significantly increased, thus reducing the p-/o-xylene separation performance. This behavior was ascribed to the flexible MFI zeolite structure after the adsorption of p-xylene.",
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AU - Richter, Hannes

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AU - Choi, Nakwon

AU - Nam, Jaewook

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AB - The defect structure in a c-out-of-plane oriented MFI membrane was quantitatively analyzed by processing images obtained by fluorescence confocal optical microscopy (FCOM). The MFI membranes were placed in contact with a dye solution at a fixed concentration (1 mM) for 2, 4, and 8 d and at different concentrations (0.01, 0.1, and 1 mM) for 8 d. This approach led to the identification and understanding of two types of defects (cracks and grain boundary defects). The representative quantitative properties (porosity and tortuosity) relevant to the defects were obtained via the image processing. Furthermore, the estimation of the defect sizes was complemented by the use of a one-dimensional permeation model for the molar flux of the p-/o-xylene components across the c-oriented MFI membrane. Using this combination, we found that although the amount of defects in the whole zeolite membrane was close to ~ 1%, they provided non-selective, facile pathways that accounted for ~ 58% of the total molar flux of faster permeating p-xylene. Surprisingly, despite the lower density (pixel-based area fraction) of cracks, wider cracks (~ 7.8–8.2 nm) accounted for the much higher molar flux of permeation components compared to major, but narrower grain boundary defects (~ 1–2 nm). Indeed, the cracks mainly deteriorated a p-/o-xylene separation performance of the c-oriented MFI membrane. Finally, we found that the crack size increased in the presence of p-xylene so that the molar flux of o-xylene in the binary mixture was significantly increased, thus reducing the p-/o-xylene separation performance. This behavior was ascribed to the flexible MFI zeolite structure after the adsorption of p-xylene.

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