Recent progress in second-order nonlinear optical polymers and dendrimers

Min Ju Cho, Dong Hoon Choi, Philip A. Sullivan, Andrew J P Akelaitis, Larry R. Dalton

Research output: Contribution to journalArticle

280 Citations (Scopus)

Abstract

This review provides a survey of nonlinear optical (NLO) chromophores and materials incorporating them which have been demonstrated over the last several years. Conventional polymeric materials, dendrimers, and other material design approaches are reviewed. Macroscopic nonlinear optical properties are introduced mainly in terms of second-harmonic generation (SHG) and the electro-optic (EO) effect. The temporal and thermal stability of nonlinear optical properties are also discussed. The review begins with a brief introduction explaining overall principles relating to the origin of second-order nonlinear optical properties. The structure of NLO materials, methods for their characterization, and structure-property relationships are also introduced. Much current research is aimed at optimizing microscopic nonlinearity in well-defined heterocyclic NLO chromophores which are then embedded in materials such as polymers, dendrimers, etc. Strong electron density donor and acceptor groups are connected through an efficient π-electron conjugative bridge to yield a highly electronically asymmetric and hyperpolarizable NLO chromophore. This review highlights the design and synthesis of recent chromophores that simultaneously exhibit large molecular hyperpolarizability, and low optical absorption at an operating wavelength, in addition to good processability and thermal/photochemical stability. Although NLO chromophores have been designed to exploit both dipolar and octupolar symmetry, the former has exhibited the strongest potential for the development of practical NLO devices. Organic materials based on polymers and dendrimers containing dipolar chromophores are mainly demonstrated for nonlinear optics. Experimental results corresponding to such dipolar compounds are mainly considered in this review. In addition, new strategies to improve thermal stabilities are also discussed herein.

Original languageEnglish
Pages (from-to)1013-1058
Number of pages46
JournalProgress in Polymer Science (Oxford)
Volume33
Issue number11
DOIs
Publication statusPublished - 2008 Nov 1

Fingerprint

Dendrimers
dendrimers
Chromophores
chromophores
Polymers
polymers
Optical properties
optical properties
Thermodynamic stability
thermal stability
Nonlinear optics
Optical materials
nonlinear optics
optical materials
Electrooptical effects
Harmonic generation
organic materials
Optical devices
Light absorption
electro-optics

Keywords

  • Dendrimer
  • Electro-optic materials
  • Noncentrosymmetry
  • Nonlinear optical chromophore
  • Polymer
  • Temporal stability

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry
  • Polymers and Plastics
  • Organic Chemistry
  • Surfaces and Interfaces

Cite this

Recent progress in second-order nonlinear optical polymers and dendrimers. / Cho, Min Ju; Choi, Dong Hoon; Sullivan, Philip A.; Akelaitis, Andrew J P; Dalton, Larry R.

In: Progress in Polymer Science (Oxford), Vol. 33, No. 11, 01.11.2008, p. 1013-1058.

Research output: Contribution to journalArticle

Cho, Min Ju ; Choi, Dong Hoon ; Sullivan, Philip A. ; Akelaitis, Andrew J P ; Dalton, Larry R. / Recent progress in second-order nonlinear optical polymers and dendrimers. In: Progress in Polymer Science (Oxford). 2008 ; Vol. 33, No. 11. pp. 1013-1058.
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