Recovery and local-variation of Dirac cones in oxygen-intercalated graphene on Ru(0001) studied using scanning tunneling microscopy and spectroscopy

Won Jun Jang, Howon Kim, Jeong Heum Jeon, Jong Keon Yoon, Se-Jong Kahng

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Methods to decouple epitaxial graphene from metal substrates have been extensively studied, with anticipation of observing unperturbed Dirac cone properties, but its local electronic structures were rarely studied. Here, we investigated the local variations of Dirac cones recovered using oxygen intercalation applied to epitaxial graphene on Ru(0001) using scanning tunneling microscopy and spectroscopy (STM and STS). New V-shaped features, which appear in the STS data at the oxygen-intercalated graphene regions, are attributed to the signatures of recovered Dirac cones. The Dirac point energy was observed at 0.48 eV below the Fermi level, different from previous photoemission results because of different oxygen coverages. The observed spatial variations of Dirac point energy were explained by the weakly protruding network structures caused by a small net strain in graphene. Our study shows that oxygen-intercalated graphene provides an excellent platform for further graphene research at the nano-meter scale with unperturbed Dirac cones.

Original languageEnglish
Pages (from-to)16019-16023
Number of pages5
JournalPhysical Chemistry Chemical Physics
Volume15
Issue number38
DOIs
Publication statusPublished - 2013 Oct 14

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Scanning Tunnelling Microscopy
Graphite
Scanning tunneling microscopy
Cones
scanning tunneling microscopy
Spectrum Analysis
cones
graphene
recovery
Spectroscopy
Oxygen
Recovery
oxygen
spectroscopy
space transportation system
Photoemission
Intercalation
Fermi level
intercalation
Electronic structure

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Physics and Astronomy(all)

Cite this

Recovery and local-variation of Dirac cones in oxygen-intercalated graphene on Ru(0001) studied using scanning tunneling microscopy and spectroscopy. / Jang, Won Jun; Kim, Howon; Jeon, Jeong Heum; Yoon, Jong Keon; Kahng, Se-Jong.

In: Physical Chemistry Chemical Physics, Vol. 15, No. 38, 14.10.2013, p. 16019-16023.

Research output: Contribution to journalArticle

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