Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties

Mai Ha Hoang; Jong Soo Ahn; Duc Nghia Nguyen; Trinh Tung Ngo; Dae Hee Lee; Min Ju Cho; Dong Hoon Choi

doi:10.1002/pola.27979

Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties

Mai Ha Hoang, Jong Soo Ahn, Duc Nghia Nguyen, Trinh Tung Ngo, Dae Hee Lee, Min Ju Cho, Dong Hoon Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Diketopyrrolopyrrole (DPP)-based terpolymers - P(DPP-TPyT) and P(DPP-T3MTT) - bearing bithiophene donating groups and weak accepting units such as pyridine (Py) or methyl thiophene-3-carboxylate (3MT), in the polymer backbone, were successfully synthesized. Although the two polymers had similar physical and electrochemical properties, grazing incidence X-ray diffraction patterns of P(DPP-TPyT) and P(DPP-T3MTT) showed mixed and edge-on orientations, respectively, in thermally annealed films. Accordingly, the P(DPP-T3MTT) showed twice the hole mobility of P(DPP-TPyT) in a thin-film transistor, and a blended film of P(DPP-T3MTT) and [6,6]-phenyl-C71-butyric acid methyl ester (PC₇₁BM) showed better power conversion efficiency in a polymer solar cell.

Original language	English
Pages (from-to)	1339-1347
Number of pages	9
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	54
Issue number	10
DOIs	https://doi.org/10.1002/pola.27979
Publication status	Published - 2016 May 15

Keywords

conjugated polymer
diketopyrrolopyrrole
organic thin film transistor
polymer solar cell
terpolymer

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

Access to Document

10.1002/pola.27979

Fingerprint Dive into the research topics of 'Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties'. Together they form a unique fingerprint.

Cite this

Hoang, M. H., Ahn, J. S., Nguyen, D. N., Ngo, T. T., Lee, D. H., Cho, M. J., & Choi, D. H. (2016). Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties. Journal of Polymer Science, Part A: Polymer Chemistry, 54(10), 1339-1347. https://doi.org/10.1002/pola.27979

Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group : Effect of strong and weak acceptors on semiconducting properties. / Hoang, Mai Ha; Ahn, Jong Soo; Nguyen, Duc Nghia; Ngo, Trinh Tung; Lee, Dae Hee; Cho, Min Ju; Choi, Dong Hoon.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 54, No. 10, 15.05.2016, p. 1339-1347.

Research output: Contribution to journal › Article › peer-review

Hoang, MH, Ahn, JS, Nguyen, DN, Ngo, TT, Lee, DH, Cho, MJ & Choi, DH 2016, 'Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties', Journal of Polymer Science, Part A: Polymer Chemistry, vol. 54, no. 10, pp. 1339-1347. https://doi.org/10.1002/pola.27979

Hoang, Mai Ha ; Ahn, Jong Soo ; Nguyen, Duc Nghia ; Ngo, Trinh Tung ; Lee, Dae Hee ; Cho, Min Ju ; Choi, Dong Hoon. / Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group : Effect of strong and weak acceptors on semiconducting properties. In: Journal of Polymer Science, Part A: Polymer Chemistry. 2016 ; Vol. 54, No. 10. pp. 1339-1347.

@article{941266cd1e784dd69ec73b784ca74c31,

title = "Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties",

abstract = "Diketopyrrolopyrrole (DPP)-based terpolymers - P(DPP-TPyT) and P(DPP-T3MTT) - bearing bithiophene donating groups and weak accepting units such as pyridine (Py) or methyl thiophene-3-carboxylate (3MT), in the polymer backbone, were successfully synthesized. Although the two polymers had similar physical and electrochemical properties, grazing incidence X-ray diffraction patterns of P(DPP-TPyT) and P(DPP-T3MTT) showed mixed and edge-on orientations, respectively, in thermally annealed films. Accordingly, the P(DPP-T3MTT) showed twice the hole mobility of P(DPP-TPyT) in a thin-film transistor, and a blended film of P(DPP-T3MTT) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) showed better power conversion efficiency in a polymer solar cell.",

keywords = "conjugated polymer, diketopyrrolopyrrole, organic thin film transistor, polymer solar cell, terpolymer",

author = "Hoang, {Mai Ha} and Ahn, {Jong Soo} and Nguyen, {Duc Nghia} and Ngo, {Trinh Tung} and Lee, {Dae Hee} and Cho, {Min Ju} and Choi, {Dong Hoon}",

note = "Funding Information: ACKNOWLEDGMENTS: This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant numbers: {"}104.02-2013.67{"} and {"}104.04.28.09{"}. The authors also acknowledge the financial support from the National Research Foundation of Korea (NRF2012R1A2A1A01008797) and from Key Research Institute Program (NRF201200020209). MJ Cho particularly acknowledges the support from a Korea University grant (2013{"}2014).",

year = "2016",

month = may,

day = "15",

doi = "10.1002/pola.27979",

language = "English",

volume = "54",

pages = "1339--1347",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley and Sons Inc.",

number = "10",

}

TY - JOUR

T1 - Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group

T2 - Effect of strong and weak acceptors on semiconducting properties

AU - Hoang, Mai Ha

AU - Ahn, Jong Soo

AU - Nguyen, Duc Nghia

AU - Ngo, Trinh Tung

AU - Lee, Dae Hee

AU - Cho, Min Ju

AU - Choi, Dong Hoon

N1 - Funding Information: ACKNOWLEDGMENTS: This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant numbers: "104.02-2013.67" and "104.04.28.09". The authors also acknowledge the financial support from the National Research Foundation of Korea (NRF2012R1A2A1A01008797) and from Key Research Institute Program (NRF201200020209). MJ Cho particularly acknowledges the support from a Korea University grant (2013"2014).

PY - 2016/5/15

Y1 - 2016/5/15

N2 - Diketopyrrolopyrrole (DPP)-based terpolymers - P(DPP-TPyT) and P(DPP-T3MTT) - bearing bithiophene donating groups and weak accepting units such as pyridine (Py) or methyl thiophene-3-carboxylate (3MT), in the polymer backbone, were successfully synthesized. Although the two polymers had similar physical and electrochemical properties, grazing incidence X-ray diffraction patterns of P(DPP-TPyT) and P(DPP-T3MTT) showed mixed and edge-on orientations, respectively, in thermally annealed films. Accordingly, the P(DPP-T3MTT) showed twice the hole mobility of P(DPP-TPyT) in a thin-film transistor, and a blended film of P(DPP-T3MTT) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) showed better power conversion efficiency in a polymer solar cell.

AB - Diketopyrrolopyrrole (DPP)-based terpolymers - P(DPP-TPyT) and P(DPP-T3MTT) - bearing bithiophene donating groups and weak accepting units such as pyridine (Py) or methyl thiophene-3-carboxylate (3MT), in the polymer backbone, were successfully synthesized. Although the two polymers had similar physical and electrochemical properties, grazing incidence X-ray diffraction patterns of P(DPP-TPyT) and P(DPP-T3MTT) showed mixed and edge-on orientations, respectively, in thermally annealed films. Accordingly, the P(DPP-T3MTT) showed twice the hole mobility of P(DPP-TPyT) in a thin-film transistor, and a blended film of P(DPP-T3MTT) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) showed better power conversion efficiency in a polymer solar cell.

KW - conjugated polymer

KW - diketopyrrolopyrrole

KW - organic thin film transistor

KW - polymer solar cell

KW - terpolymer

UR - http://www.scopus.com/inward/record.url?scp=84962050639&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84962050639&partnerID=8YFLogxK

U2 - 10.1002/pola.27979

DO - 10.1002/pola.27979

M3 - Article

AN - SCOPUS:84962050639

VL - 54

SP - 1339

EP - 1347

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 10

ER -

Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this