Removal and co-transport of Zn, As(V), and Cd during leachate seepage through downgradient mine soils: A batch sorption and column study

Juhee Kim, Seung Mo Nam, Seunghun Hyun

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The removal of Zn, As(V), and Cd during the leachate seepage process was measured in single, binary, and ternary solute systems by batch sorption and 1-column flow experiments, followed by a sequential extraction procedure (SEP). In single-solute systems, sorption (Kd *) occurred in the order of As(V) > Zn ≫ Cd, and this sequence did not change in the presence of other solutes. In multi-solute systems, the sorption of Zn (~20%) and Cd (~27%) was enhanced by As(V), while Zn and Cd suppressed the sorption of each other. In all cases, As(V) sorption was not affected by the cations, indicating that As(V) is prioritized by sorption sites to a much greater degree than Zn and Cd. Element retention by column soils was strongly correlated (r2 = 0.77) with Kd *. Across column segments, mass retention was in the order of inlet (36-54%) > middle (26-35%) > outlet (20-31%), except for Cd in the Zn-Cd binary system. The result of SEP revealed that most of the retained Cd (98-99%) and Zn (56-71%) was in the labile fraction (e.g., the sum of F1 and F2) while only 9-12% of As(V) was labile and most (>55%) was specifically adsorbed to Fe/Al oxides. Plots of the labile fraction (flabile) and the fast sorption fraction (ffast) suggested that the kinetics of specific As(V) sorption occur rapidly (ffast > flabile), whereas labile Zn and Cd sorption occurs slowly (flabile > ffast), indicating the occurrence of kinetically limited labile sorption sites, probably due to Zn-Cd competition. In conclusion, the element leaching potential of mine leachate can be greatly attenuated during downgradient soil seepage. However, when assessing the soil attenuation process, the impact of sorption competitors and the lability of adsorbed elements should first be considered.

Original languageEnglish
Pages (from-to)571-578
Number of pages8
JournalScience of the Total Environment
Volume551-552
DOIs
Publication statusPublished - 2016 May 1

Fingerprint

Seepage
seepage
leachate
Sorption
sorption
Soils
soil
solute
removal
soil column
Oxides
Leaching
Cations
cation
Positive ions
leaching
oxide

Keywords

  • Cosolute
  • Metallic elements
  • Mine leachate
  • Seepage
  • Soil attenuation

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution
  • Waste Management and Disposal
  • Environmental Engineering

Cite this

Removal and co-transport of Zn, As(V), and Cd during leachate seepage through downgradient mine soils : A batch sorption and column study. / Kim, Juhee; Nam, Seung Mo; Hyun, Seunghun.

In: Science of the Total Environment, Vol. 551-552, 01.05.2016, p. 571-578.

Research output: Contribution to journalArticle

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abstract = "The removal of Zn, As(V), and Cd during the leachate seepage process was measured in single, binary, and ternary solute systems by batch sorption and 1-column flow experiments, followed by a sequential extraction procedure (SEP). In single-solute systems, sorption (Kd *) occurred in the order of As(V) > Zn ≫ Cd, and this sequence did not change in the presence of other solutes. In multi-solute systems, the sorption of Zn (~20{\%}) and Cd (~27{\%}) was enhanced by As(V), while Zn and Cd suppressed the sorption of each other. In all cases, As(V) sorption was not affected by the cations, indicating that As(V) is prioritized by sorption sites to a much greater degree than Zn and Cd. Element retention by column soils was strongly correlated (r2 = 0.77) with Kd *. Across column segments, mass retention was in the order of inlet (36-54{\%}) > middle (26-35{\%}) > outlet (20-31{\%}), except for Cd in the Zn-Cd binary system. The result of SEP revealed that most of the retained Cd (98-99{\%}) and Zn (56-71{\%}) was in the labile fraction (e.g., the sum of F1 and F2) while only 9-12{\%} of As(V) was labile and most (>55{\%}) was specifically adsorbed to Fe/Al oxides. Plots of the labile fraction (flabile) and the fast sorption fraction (ffast) suggested that the kinetics of specific As(V) sorption occur rapidly (ffast > flabile), whereas labile Zn and Cd sorption occurs slowly (flabile > ffast), indicating the occurrence of kinetically limited labile sorption sites, probably due to Zn-Cd competition. In conclusion, the element leaching potential of mine leachate can be greatly attenuated during downgradient soil seepage. However, when assessing the soil attenuation process, the impact of sorption competitors and the lability of adsorbed elements should first be considered.",
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