Removal of heavy metal ions from water by cross-linked carboxymethyl corn starch

B. S. Kirn, Seung Taik Lim

Research output: Contribution to journalArticle

98 Citations (Scopus)

Abstract

Corn starch after cross-linking with POCl 3 (1%, v/w, starch db) was carboxymethylated with sodium chloroacetate (5-20%, v/w, starch db) to examine the metal removal activity of the starch from water. The cross-linked carboxymethyl starch [degree of substitution (DS) 0.02-0.08] was dispersed (0.5-3.0%) in aqueous solutions of divalent metal ions (Cu, Pb, Cd and Hg, approximately 200 ppm), and the starch-metal complex was filtered. Removal efficiency of the metal ions from their aqueous solutions increased proportionally with the DS of the carboxymethyl group and the starch content in the solution. Ionization of the carboxymethyl groups in starch was necessary for the effective metal removal. When the starch pH was adjusted below 4.0 after carboxymethylation, the starch was no longer an effective metal binder. The metal ions interacted with starch, 10 min after the starch was added. Lead, cadmium, and mercury ions in water were almost completely removed when 1% starch (DS 0.081, pH 6.0) was used. Under the same conditions, copper concentration was reduced from 203 to 71 ppm. Starch could be recovered by washing the metal ions from the complex with weak acid (pH 2.0) although the metal-binding activity of the starch was slightly reduced by this process.

Original languageEnglish
Pages (from-to)217-223
Number of pages7
JournalCarbohydrate Polymers
Volume39
Issue number3
DOIs
Publication statusPublished - 1999 Jul 1

Fingerprint

Heavy Ions
Heavy Metals
corn starch
Starch
Heavy ions
metal ions
Heavy metals
Zea mays
Metal ions
heavy metals
starch
Water
Metals
water
Ions
metals
Coordination Complexes
Substitution reactions
carboxymethyl starch
aqueous solutions

ASJC Scopus subject areas

  • Food Science
  • Biochemistry

Cite this

Removal of heavy metal ions from water by cross-linked carboxymethyl corn starch. / Kirn, B. S.; Lim, Seung Taik.

In: Carbohydrate Polymers, Vol. 39, No. 3, 01.07.1999, p. 217-223.

Research output: Contribution to journalArticle

@article{f2ec88bae6da4483ab53d64c5dc64d9c,
title = "Removal of heavy metal ions from water by cross-linked carboxymethyl corn starch",
abstract = "Corn starch after cross-linking with POCl 3 (1{\%}, v/w, starch db) was carboxymethylated with sodium chloroacetate (5-20{\%}, v/w, starch db) to examine the metal removal activity of the starch from water. The cross-linked carboxymethyl starch [degree of substitution (DS) 0.02-0.08] was dispersed (0.5-3.0{\%}) in aqueous solutions of divalent metal ions (Cu, Pb, Cd and Hg, approximately 200 ppm), and the starch-metal complex was filtered. Removal efficiency of the metal ions from their aqueous solutions increased proportionally with the DS of the carboxymethyl group and the starch content in the solution. Ionization of the carboxymethyl groups in starch was necessary for the effective metal removal. When the starch pH was adjusted below 4.0 after carboxymethylation, the starch was no longer an effective metal binder. The metal ions interacted with starch, 10 min after the starch was added. Lead, cadmium, and mercury ions in water were almost completely removed when 1{\%} starch (DS 0.081, pH 6.0) was used. Under the same conditions, copper concentration was reduced from 203 to 71 ppm. Starch could be recovered by washing the metal ions from the complex with weak acid (pH 2.0) although the metal-binding activity of the starch was slightly reduced by this process.",
author = "Kirn, {B. S.} and Lim, {Seung Taik}",
year = "1999",
month = "7",
day = "1",
doi = "10.1016/S0144-8617(99)00011-9",
language = "English",
volume = "39",
pages = "217--223",
journal = "Carbohydrate Polymers",
issn = "0144-8617",
publisher = "Elsevier Limited",
number = "3",

}

TY - JOUR

T1 - Removal of heavy metal ions from water by cross-linked carboxymethyl corn starch

AU - Kirn, B. S.

AU - Lim, Seung Taik

PY - 1999/7/1

Y1 - 1999/7/1

N2 - Corn starch after cross-linking with POCl 3 (1%, v/w, starch db) was carboxymethylated with sodium chloroacetate (5-20%, v/w, starch db) to examine the metal removal activity of the starch from water. The cross-linked carboxymethyl starch [degree of substitution (DS) 0.02-0.08] was dispersed (0.5-3.0%) in aqueous solutions of divalent metal ions (Cu, Pb, Cd and Hg, approximately 200 ppm), and the starch-metal complex was filtered. Removal efficiency of the metal ions from their aqueous solutions increased proportionally with the DS of the carboxymethyl group and the starch content in the solution. Ionization of the carboxymethyl groups in starch was necessary for the effective metal removal. When the starch pH was adjusted below 4.0 after carboxymethylation, the starch was no longer an effective metal binder. The metal ions interacted with starch, 10 min after the starch was added. Lead, cadmium, and mercury ions in water were almost completely removed when 1% starch (DS 0.081, pH 6.0) was used. Under the same conditions, copper concentration was reduced from 203 to 71 ppm. Starch could be recovered by washing the metal ions from the complex with weak acid (pH 2.0) although the metal-binding activity of the starch was slightly reduced by this process.

AB - Corn starch after cross-linking with POCl 3 (1%, v/w, starch db) was carboxymethylated with sodium chloroacetate (5-20%, v/w, starch db) to examine the metal removal activity of the starch from water. The cross-linked carboxymethyl starch [degree of substitution (DS) 0.02-0.08] was dispersed (0.5-3.0%) in aqueous solutions of divalent metal ions (Cu, Pb, Cd and Hg, approximately 200 ppm), and the starch-metal complex was filtered. Removal efficiency of the metal ions from their aqueous solutions increased proportionally with the DS of the carboxymethyl group and the starch content in the solution. Ionization of the carboxymethyl groups in starch was necessary for the effective metal removal. When the starch pH was adjusted below 4.0 after carboxymethylation, the starch was no longer an effective metal binder. The metal ions interacted with starch, 10 min after the starch was added. Lead, cadmium, and mercury ions in water were almost completely removed when 1% starch (DS 0.081, pH 6.0) was used. Under the same conditions, copper concentration was reduced from 203 to 71 ppm. Starch could be recovered by washing the metal ions from the complex with weak acid (pH 2.0) although the metal-binding activity of the starch was slightly reduced by this process.

UR - http://www.scopus.com/inward/record.url?scp=0032685795&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032685795&partnerID=8YFLogxK

U2 - 10.1016/S0144-8617(99)00011-9

DO - 10.1016/S0144-8617(99)00011-9

M3 - Article

VL - 39

SP - 217

EP - 223

JO - Carbohydrate Polymers

JF - Carbohydrate Polymers

SN - 0144-8617

IS - 3

ER -