Resonant coherent hyper-Raman scattering (CHRS). II. A theory on the general relationship between CHRS and coherent Raman scattering (CRS) processes

Minhaeng Cho

doi:10.1063/1.476787

Resonant coherent hyper-Raman scattering (CHRS). II. A theory on the general relationship between CHRS and coherent Raman scattering (CRS) processes

Minhaeng Cho

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A theoretical description of the resonant coherent hyper-Raman scattering for an arbitrary system-bath interaction is presented. Particularly the relationship between the coherent hyper-Raman scattering (CHRS) and coherent Raman scattering (CRS) signals is established without alluding to any specific model of optical broadening. The permanent dipole moment difference between the excited and ground states of a given chromophore is shown to be proportional to the ratio of the CHRS to CRS signals, and it is proved that this result is valid regardless of the model for the chromophore-bath interaction.

Original language	English
Pages (from-to)	2194-2201
Number of pages	8
Journal	Journal of Chemical Physics
Volume	109
Issue number	6
DOIs	https://doi.org/10.1063/1.476787
Publication status	Published - 1998

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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AB - A theoretical description of the resonant coherent hyper-Raman scattering for an arbitrary system-bath interaction is presented. Particularly the relationship between the coherent hyper-Raman scattering (CHRS) and coherent Raman scattering (CRS) signals is established without alluding to any specific model of optical broadening. The permanent dipole moment difference between the excited and ground states of a given chromophore is shown to be proportional to the ratio of the CHRS to CRS signals, and it is proved that this result is valid regardless of the model for the chromophore-bath interaction.

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Resonant coherent hyper-Raman scattering (CHRS). II. A theory on the general relationship between CHRS and coherent Raman scattering (CRS) processes

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