Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal–organic framework

Euna Jeong, Woo Ram Lee, Dae Won Ryu, Yeonga Kim, Won Ju Phang, Eui Kwan Koh, Chang Seop Hong

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

An aqua-bridged Mn metal–organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange–resolvation and desolvation–resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N2, H2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units.

Original languageEnglish
Pages (from-to)2329-2331
Number of pages3
JournalChemical Communications
Volume49
Issue number23
DOIs
Publication statusPublished - 2013 Feb 21

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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