Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal-organic framework

Euna Jeong, Woo Ram Lee, Dae Won Ryu, Yeonga Kim, Won Ju Phang, Eui Kwan Koh, Chang Seop Hong

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N2, H2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units. This journal is

Original languageEnglish
Pages (from-to)2329-2331
Number of pages3
JournalChemical Communications
Volume49
Issue number23
DOIs
Publication statusPublished - 2013 Mar 21

Fingerprint

Gas adsorption
Adsorption
Gases
Metals

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal-organic framework. / Jeong, Euna; Lee, Woo Ram; Ryu, Dae Won; Kim, Yeonga; Phang, Won Ju; Koh, Eui Kwan; Hong, Chang Seop.

In: Chemical Communications, Vol. 49, No. 23, 21.03.2013, p. 2329-2331.

Research output: Contribution to journalArticle

Jeong, Euna ; Lee, Woo Ram ; Ryu, Dae Won ; Kim, Yeonga ; Phang, Won Ju ; Koh, Eui Kwan ; Hong, Chang Seop. / Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal-organic framework. In: Chemical Communications. 2013 ; Vol. 49, No. 23. pp. 2329-2331.
@article{b738961db62246419eb0c6e8b08a804b,
title = "Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal-organic framework",
abstract = "An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N2, H2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units. This journal is",
author = "Euna Jeong and Lee, {Woo Ram} and Ryu, {Dae Won} and Yeonga Kim and Phang, {Won Ju} and Koh, {Eui Kwan} and Hong, {Chang Seop}",
year = "2013",
month = "3",
day = "21",
doi = "10.1039/c3cc00093a",
language = "English",
volume = "49",
pages = "2329--2331",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "23",

}

TY - JOUR

T1 - Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(ii) metal-organic framework

AU - Jeong, Euna

AU - Lee, Woo Ram

AU - Ryu, Dae Won

AU - Kim, Yeonga

AU - Phang, Won Ju

AU - Koh, Eui Kwan

AU - Hong, Chang Seop

PY - 2013/3/21

Y1 - 2013/3/21

N2 - An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N2, H2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units. This journal is

AB - An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO2 uptake over N2, H2, and CH4. Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units. This journal is

UR - http://www.scopus.com/inward/record.url?scp=84875932517&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84875932517&partnerID=8YFLogxK

U2 - 10.1039/c3cc00093a

DO - 10.1039/c3cc00093a

M3 - Article

VL - 49

SP - 2329

EP - 2331

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 23

ER -