Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework

Kwangyeol Lee, Scott R. Wilson, John R. Shapley

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Oxidative substitution of [Ru10C2(CO)22-(NBD)]2- with ferrocenium ion and diazomethane forms a methylene compound, Ru10C2(CO)22(NBD)(μ-CH2), in which the methylene ligand symmetrically bridges two adjacent apical ruthenium centers in the edge-fused bioctahedral Ru10C2 framework. A methylidyne tautomer, Ru10C2(CO)22(NBD)(CH)(H), is formed reversibly at 80°C.

Original languageEnglish
Pages (from-to)4113-4116
Number of pages4
JournalOrganometallics
Volume17
Issue number18
Publication statusPublished - 1998 Aug 31
Externally publishedYes

Fingerprint

Diazomethane
Ruthenium
methylene
Hydrides
hydrides
Substitution reactions
methylidyne
Ions
Ligands
tautomers
ruthenium
substitutes
ligands
ions
ferrocenium

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework. / Lee, Kwangyeol; Wilson, Scott R.; Shapley, John R.

In: Organometallics, Vol. 17, No. 18, 31.08.1998, p. 4113-4116.

Research output: Contribution to journalArticle

Lee, Kwangyeol ; Wilson, Scott R. ; Shapley, John R. / Reversible transformation between methylene and methylidyne-hydride moieties on the Ru10C2 framework. In: Organometallics. 1998 ; Vol. 17, No. 18. pp. 4113-4116.
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