Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray, Chang Seop Hong, Swastik Mondal, Monika Mukherjee, Mahammad Ali

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

X-ray structural analysis shows that {[Cu2(CTA) (H2O)] · 5 H2O}n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm-1) and antiferromagnetic (J = -2.5 cm-1) interactions.

Original languageEnglish
Pages (from-to)527-530
Number of pages4
JournalInorganic Chemistry Communications
Volume10
Issue number5
DOIs
Publication statusPublished - 2007 May

Keywords

  • Alternate ferro- and antiferromagnetic interactions
  • Inclusion chemistry
  • Metal-organic frameworks
  • X-ray structural characterization

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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