Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions

Ambarish Ray, Chang Seop Hong, Swastik Mondal, Monika Mukherjee, Mahammad Ali

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

X-ray structural analysis shows that {[Cu 2(CTA) (H 2O)] · 5 H 2O} n constitutes infinite one-dimensional parallel chains along the c-axis with water columns running down the crystallographic a-axis. The inclusion of water molecules is reversible and is confirmed by X-ray powder diffraction studies. The magnetic data (2-300 K) reveal that there are alternate ferro- (J = 0.29 cm -1) and antiferromagnetic (J = -2.5 cm -1) interactions.

Original languageEnglish
Pages (from-to)527-530
Number of pages4
JournalInorganic Chemistry Communications
Volume10
Issue number5
DOIs
Publication statusPublished - 2007 May 1

Fingerprint

Magnetic materials
magnetic materials
Porous materials
Copper
Metals
inclusions
Powder Diffraction
copper
Water
structural analysis
Structural analysis
X-Ray Diffraction
metals
X ray powder diffraction
water
x rays
X-Rays
interactions
X rays
Molecules

Keywords

  • Alternate ferro- and antiferromagnetic interactions
  • Inclusion chemistry
  • Metal-organic frameworks
  • X-ray structural characterization

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Reversible water inclusion in a porous magnetic material synthesized from copper(II) incorporated metal-organic framework showing alternate ferro- and antiferromagnetic interactions. / Ray, Ambarish; Hong, Chang Seop; Mondal, Swastik; Mukherjee, Monika; Ali, Mahammad.

In: Inorganic Chemistry Communications, Vol. 10, No. 5, 01.05.2007, p. 527-530.

Research output: Contribution to journalArticle

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