Rh-Ni and Rh-Co catalysts for autothermal reforming of gasoline

Yeon Gyu Jung; Dae Hyung Lee; Yongmin Kim; Jin Hee Lee; Suk Woo Nam; Dae Ki Choi; Chang Won Yoon

doi:10.5012/bkcs.2014.35.1.231

Rh-Ni and Rh-Co catalysts for autothermal reforming of gasoline

Yeon Gyu Jung, Dae Hyung Lee, Yongmin Kim, Jin Hee Lee, Suk Woo Nam, Dae Ki Choi, Chang Won Yoon

GREEN SCHOOL (Graduate School of Energy and Environment)

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Rh doped Ni and Co catalysts, Rh-M/CeO₂(20 wt %)-Al ₂O₃ (0.2 wt % of Rh; M = Ni or Co, 20 wt %) were synthesized to produce hydrogen via autothermal reforming (ATR) of commercial gasoline at 700 oC under the conditions of a S/C ratio of 2.0, an O/C ratio of 0.84, and a gas hourly space velocity (GHSV) of 20,000 h-1. The Rh-Ni/CeO ₂(20 wt %)-Al₂O₃ catalyst (1) exhibited excellent activities, with H₂ and (H₂+CO) yields of 2.04 and 2.58 mol/mol C, respectively. In addition, this catalyst proved to be highly stable over 100 h without catalyst deactivation, as evidenced by energy dispersive spectroscopy (EDX) and elemental analyses. Compared to 1, Rh-Co/CeO₂(20 wt %)-Al₂O₃ catalyst (2) exhibited relatively low stability, and its activity decreased after 57 h. In line with this observation, elemental analyses confirmed that nearly no carbon species were formed at 1 while carbon deposits (10 wt %) were found at 2 following the reaction, which suggests that carbon coking is the main process for catalyst deactivation.

Original language	English
Pages (from-to)	231-235
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	35
Issue number	1
DOIs	https://doi.org/10.5012/bkcs.2014.35.1.231
Publication status	Published - 2014 Jan 20

Keywords

Autothermal reforming
Bimetallic catalyst
Carbon coking
CeO-Al O Gasoline

ASJC Scopus subject areas

Chemistry(all)

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@article{e3957193b0014720a74b233f76937e70,

title = "Rh-Ni and Rh-Co catalysts for autothermal reforming of gasoline",

abstract = "Rh doped Ni and Co catalysts, Rh-M/CeO2(20 wt %)-Al 2O3 (0.2 wt % of Rh; M = Ni or Co, 20 wt %) were synthesized to produce hydrogen via autothermal reforming (ATR) of commercial gasoline at 700 oC under the conditions of a S/C ratio of 2.0, an O/C ratio of 0.84, and a gas hourly space velocity (GHSV) of 20,000 h-1. The Rh-Ni/CeO 2(20 wt %)-Al2O3 catalyst (1) exhibited excellent activities, with H2 and (H2+CO) yields of 2.04 and 2.58 mol/mol C, respectively. In addition, this catalyst proved to be highly stable over 100 h without catalyst deactivation, as evidenced by energy dispersive spectroscopy (EDX) and elemental analyses. Compared to 1, Rh-Co/CeO2(20 wt %)-Al2O3 catalyst (2) exhibited relatively low stability, and its activity decreased after 57 h. In line with this observation, elemental analyses confirmed that nearly no carbon species were formed at 1 while carbon deposits (10 wt %) were found at 2 following the reaction, which suggests that carbon coking is the main process for catalyst deactivation.",

keywords = "Autothermal reforming, Bimetallic catalyst, Carbon coking, CeO-Al O Gasoline",

author = "Jung, {Yeon Gyu} and Lee, {Dae Hyung} and Yongmin Kim and Lee, {Jin Hee} and Nam, {Suk Woo} and Choi, {Dae Ki} and Yoon, {Chang Won}",

year = "2014",

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doi = "10.5012/bkcs.2014.35.1.231",

language = "English",

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TY - JOUR

T1 - Rh-Ni and Rh-Co catalysts for autothermal reforming of gasoline

AU - Jung, Yeon Gyu

AU - Lee, Dae Hyung

AU - Kim, Yongmin

AU - Lee, Jin Hee

AU - Nam, Suk Woo

AU - Choi, Dae Ki

AU - Yoon, Chang Won

PY - 2014/1/20

Y1 - 2014/1/20

N2 - Rh doped Ni and Co catalysts, Rh-M/CeO2(20 wt %)-Al 2O3 (0.2 wt % of Rh; M = Ni or Co, 20 wt %) were synthesized to produce hydrogen via autothermal reforming (ATR) of commercial gasoline at 700 oC under the conditions of a S/C ratio of 2.0, an O/C ratio of 0.84, and a gas hourly space velocity (GHSV) of 20,000 h-1. The Rh-Ni/CeO 2(20 wt %)-Al2O3 catalyst (1) exhibited excellent activities, with H2 and (H2+CO) yields of 2.04 and 2.58 mol/mol C, respectively. In addition, this catalyst proved to be highly stable over 100 h without catalyst deactivation, as evidenced by energy dispersive spectroscopy (EDX) and elemental analyses. Compared to 1, Rh-Co/CeO2(20 wt %)-Al2O3 catalyst (2) exhibited relatively low stability, and its activity decreased after 57 h. In line with this observation, elemental analyses confirmed that nearly no carbon species were formed at 1 while carbon deposits (10 wt %) were found at 2 following the reaction, which suggests that carbon coking is the main process for catalyst deactivation.

AB - Rh doped Ni and Co catalysts, Rh-M/CeO2(20 wt %)-Al 2O3 (0.2 wt % of Rh; M = Ni or Co, 20 wt %) were synthesized to produce hydrogen via autothermal reforming (ATR) of commercial gasoline at 700 oC under the conditions of a S/C ratio of 2.0, an O/C ratio of 0.84, and a gas hourly space velocity (GHSV) of 20,000 h-1. The Rh-Ni/CeO 2(20 wt %)-Al2O3 catalyst (1) exhibited excellent activities, with H2 and (H2+CO) yields of 2.04 and 2.58 mol/mol C, respectively. In addition, this catalyst proved to be highly stable over 100 h without catalyst deactivation, as evidenced by energy dispersive spectroscopy (EDX) and elemental analyses. Compared to 1, Rh-Co/CeO2(20 wt %)-Al2O3 catalyst (2) exhibited relatively low stability, and its activity decreased after 57 h. In line with this observation, elemental analyses confirmed that nearly no carbon species were formed at 1 while carbon deposits (10 wt %) were found at 2 following the reaction, which suggests that carbon coking is the main process for catalyst deactivation.

KW - Autothermal reforming

KW - Bimetallic catalyst

KW - Carbon coking

KW - CeO-Al O Gasoline

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JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

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ER -

Rh-Ni and Rh-Co catalysts for autothermal reforming of gasoline

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