Role of oxbow lakes in controlling redox geochemistry of shallow groundwater under a heterogeneous fluvial sedimentary environment in an agricultural field

Coexistence of iron and sulfate reduction

Byoung Young Choi, Seong Taek Yun, Kyoung Ho Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

This study aimed to extend the knowledge of the vertical distribution of redox conditions of shallow groundwater in heterogeneous fluvial sediments near oxbow lakes. For this study, we revisited the study area of Kim et al. (2009) to examine the redox zoning in details. Three multi-level samplers were installed along a flow path near two oxbow lakes to obtain vertical profiles of the subsurface geology and hydrochemical and isotopic data (δ18O and δD of water, δ15N and δ18O of nitrate, and δ34S of sulfate) of groundwater. Geologic logging showed that characteristics of the heterogeneous subsurface geology are closely related to the pattern of vertical redox zoning. Hydrochemical data in conjunction with nitrogen and sulfur isotope data show that the redox status of groundwater near oxbow lakes is controlled by denitrification, iron reduction, and sulfate reduction. The oxidizing condition of groundwater occurs in the sand-dominant alluvium located in the up-gradient of oxbow lakes, whereas the reducing condition accompanying denitrification, iron reduction, and local sulfate reduction is developed in silt-rich alluvium in and the downgradient of oxbow lakes. The occurrence of sulfate reduction was newly found in this study. However, the vertical profiles of redox-sensitive parameters show that iron reduction and sulfate reduction occur concurrently near oxbow lakes, although the measured redox potentials suggest that thermodynamic conditions are controlled by the stability of Fe2 +/Fe-oxides. Therefore, this study shows that the redox condition of groundwater in the iron-rich zone should be carefully interpreted. For this purpose, depth-specific sampling and careful examination of sulfur isotope data will be very useful for identifying the redox processes occurring in the zone with overlapping iron reduction and sulfate reduction in heterogeneous fluvial sediments.

Original languageEnglish
Pages (from-to)28-41
Number of pages14
JournalJournal of Contaminant Hydrology
Volume185-186
DOIs
Publication statusPublished - 2016 Feb 1

Fingerprint

oxbow lake
Geochemistry
Groundwater
Lakes
Sulfates
coexistence
Oxidation-Reduction
Iron
geochemistry
sulfate
iron
groundwater
Sulfur Isotopes
alluvial deposit
Geology
Denitrification
Zoning
sulfur isotope
redox conditions
vertical profile

Keywords

  • Heterogeneous fluvial aquifer
  • Isotopes
  • Multi-level sampling
  • Redox geochemistry

ASJC Scopus subject areas

  • Water Science and Technology
  • Environmental Chemistry

Cite this

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title = "Role of oxbow lakes in controlling redox geochemistry of shallow groundwater under a heterogeneous fluvial sedimentary environment in an agricultural field: Coexistence of iron and sulfate reduction",
abstract = "This study aimed to extend the knowledge of the vertical distribution of redox conditions of shallow groundwater in heterogeneous fluvial sediments near oxbow lakes. For this study, we revisited the study area of Kim et al. (2009) to examine the redox zoning in details. Three multi-level samplers were installed along a flow path near two oxbow lakes to obtain vertical profiles of the subsurface geology and hydrochemical and isotopic data (δ18O and δD of water, δ15N and δ18O of nitrate, and δ34S of sulfate) of groundwater. Geologic logging showed that characteristics of the heterogeneous subsurface geology are closely related to the pattern of vertical redox zoning. Hydrochemical data in conjunction with nitrogen and sulfur isotope data show that the redox status of groundwater near oxbow lakes is controlled by denitrification, iron reduction, and sulfate reduction. The oxidizing condition of groundwater occurs in the sand-dominant alluvium located in the up-gradient of oxbow lakes, whereas the reducing condition accompanying denitrification, iron reduction, and local sulfate reduction is developed in silt-rich alluvium in and the downgradient of oxbow lakes. The occurrence of sulfate reduction was newly found in this study. However, the vertical profiles of redox-sensitive parameters show that iron reduction and sulfate reduction occur concurrently near oxbow lakes, although the measured redox potentials suggest that thermodynamic conditions are controlled by the stability of Fe2 +/Fe-oxides. Therefore, this study shows that the redox condition of groundwater in the iron-rich zone should be carefully interpreted. For this purpose, depth-specific sampling and careful examination of sulfur isotope data will be very useful for identifying the redox processes occurring in the zone with overlapping iron reduction and sulfate reduction in heterogeneous fluvial sediments.",
keywords = "Heterogeneous fluvial aquifer, Isotopes, Multi-level sampling, Redox geochemistry",
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T1 - Role of oxbow lakes in controlling redox geochemistry of shallow groundwater under a heterogeneous fluvial sedimentary environment in an agricultural field

T2 - Coexistence of iron and sulfate reduction

AU - Choi, Byoung Young

AU - Yun, Seong Taek

AU - Kim, Kyoung Ho

PY - 2016/2/1

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N2 - This study aimed to extend the knowledge of the vertical distribution of redox conditions of shallow groundwater in heterogeneous fluvial sediments near oxbow lakes. For this study, we revisited the study area of Kim et al. (2009) to examine the redox zoning in details. Three multi-level samplers were installed along a flow path near two oxbow lakes to obtain vertical profiles of the subsurface geology and hydrochemical and isotopic data (δ18O and δD of water, δ15N and δ18O of nitrate, and δ34S of sulfate) of groundwater. Geologic logging showed that characteristics of the heterogeneous subsurface geology are closely related to the pattern of vertical redox zoning. Hydrochemical data in conjunction with nitrogen and sulfur isotope data show that the redox status of groundwater near oxbow lakes is controlled by denitrification, iron reduction, and sulfate reduction. The oxidizing condition of groundwater occurs in the sand-dominant alluvium located in the up-gradient of oxbow lakes, whereas the reducing condition accompanying denitrification, iron reduction, and local sulfate reduction is developed in silt-rich alluvium in and the downgradient of oxbow lakes. The occurrence of sulfate reduction was newly found in this study. However, the vertical profiles of redox-sensitive parameters show that iron reduction and sulfate reduction occur concurrently near oxbow lakes, although the measured redox potentials suggest that thermodynamic conditions are controlled by the stability of Fe2 +/Fe-oxides. Therefore, this study shows that the redox condition of groundwater in the iron-rich zone should be carefully interpreted. For this purpose, depth-specific sampling and careful examination of sulfur isotope data will be very useful for identifying the redox processes occurring in the zone with overlapping iron reduction and sulfate reduction in heterogeneous fluvial sediments.

AB - This study aimed to extend the knowledge of the vertical distribution of redox conditions of shallow groundwater in heterogeneous fluvial sediments near oxbow lakes. For this study, we revisited the study area of Kim et al. (2009) to examine the redox zoning in details. Three multi-level samplers were installed along a flow path near two oxbow lakes to obtain vertical profiles of the subsurface geology and hydrochemical and isotopic data (δ18O and δD of water, δ15N and δ18O of nitrate, and δ34S of sulfate) of groundwater. Geologic logging showed that characteristics of the heterogeneous subsurface geology are closely related to the pattern of vertical redox zoning. Hydrochemical data in conjunction with nitrogen and sulfur isotope data show that the redox status of groundwater near oxbow lakes is controlled by denitrification, iron reduction, and sulfate reduction. The oxidizing condition of groundwater occurs in the sand-dominant alluvium located in the up-gradient of oxbow lakes, whereas the reducing condition accompanying denitrification, iron reduction, and local sulfate reduction is developed in silt-rich alluvium in and the downgradient of oxbow lakes. The occurrence of sulfate reduction was newly found in this study. However, the vertical profiles of redox-sensitive parameters show that iron reduction and sulfate reduction occur concurrently near oxbow lakes, although the measured redox potentials suggest that thermodynamic conditions are controlled by the stability of Fe2 +/Fe-oxides. Therefore, this study shows that the redox condition of groundwater in the iron-rich zone should be carefully interpreted. For this purpose, depth-specific sampling and careful examination of sulfur isotope data will be very useful for identifying the redox processes occurring in the zone with overlapping iron reduction and sulfate reduction in heterogeneous fluvial sediments.

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KW - Redox geochemistry

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VL - 185-186

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JO - Journal of Contaminant Hydrology

JF - Journal of Contaminant Hydrology

SN - 0169-7722

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