Room-Temperature Metallic Fusion-Induced Layer-by-Layer Assembly for Highly Flexible Electrode Applications

Yongkwon Song, Donghee Kim, Sungkun Kang, Younji Ko, Jongkuk Ko, June Huh, Yongmin Ko, Seung Woo Lee, Jinhan Cho

Research output: Contribution to journalArticle

Abstract

To fabricate flexible electrodes, conventional silver (Ag) nanomaterials have been deposited onto flexible substrates, but the formed electrodes display limited electrical conductivity due to residual bulky organic ligands, and thus postsintering processes are required to improve the electrical conductivity. Herein, an entirely different approach is introduced to produce highly flexible electrodes with bulk metal–like electrical conductivity: the room-temperature metallic fusion of multilayered silver nanoparticles (NPs). Synthesized tetraoctylammonium thiosulfate (TOAS)-stabilized Ag NPs are deposited onto flexible substrates by layer-by-layer assembly involving a perfect ligand-exchange reaction between bulky TOAS ligands and small tris(2-aminoethyl)amine linkers. The introduced small linkers substantially reduce the separation distance between neighboring Ag NPs. This shortened interparticle distance, combined with the low cohesive energy of Ag NPs, strongly induces metallic fusion between the close-packed Ag NPs at room temperature without additional treatments, resulting in a high electrical conductivity of ≈1.60 × 10 5 S cm −1 (bulk Ag: ≈6.30 × 10 5 S cm −1 ). Furthermore, depositing the TOAS–Ag NPs onto cellulose papers through this approach can convert the insulating substrates into highly flexible and conductive papers that can be used as 3D current collectors for energy-storage devices.

Original languageEnglish
Article number1806584
JournalAdvanced Functional Materials
DOIs
Publication statusPublished - 2019 Jan 1

Fingerprint

Fusion reactions
assembly
fusion
Nanoparticles
nanoparticles
Electrodes
electrodes
room temperature
Thiosulfates
electrical resistivity
Ligands
Silver
Temperature
ligands
Substrates
silver
energy storage
cellulose
Nanostructured materials
Cellulose

Keywords

  • energy-storage electrodes
  • flexible electrodes
  • layer-by-layer assembly
  • room-temperature metallic fusion
  • tetraoctylammonium thiosulfate-stabilized silver nanoparticles

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Room-Temperature Metallic Fusion-Induced Layer-by-Layer Assembly for Highly Flexible Electrode Applications. / Song, Yongkwon; Kim, Donghee; Kang, Sungkun; Ko, Younji; Ko, Jongkuk; Huh, June; Ko, Yongmin; Lee, Seung Woo; Cho, Jinhan.

In: Advanced Functional Materials, 01.01.2019.

Research output: Contribution to journalArticle

Song, Yongkwon ; Kim, Donghee ; Kang, Sungkun ; Ko, Younji ; Ko, Jongkuk ; Huh, June ; Ko, Yongmin ; Lee, Seung Woo ; Cho, Jinhan. / Room-Temperature Metallic Fusion-Induced Layer-by-Layer Assembly for Highly Flexible Electrode Applications. In: Advanced Functional Materials. 2019.
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